Effect of La 3+ substitution with Gd 3+ on the resistive switching properties of La 0.7 Sr 0.3 MnO 3 thin films

Hong Sub Lee, Chang Sun Park, Hyung-Ho Park

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

This study demonstrated that the resistive switching voltage of perovskite manganite material could be controlled by A-site cation substitution in "A" MnO 3 perovskite manganite structure. A partial substitution of La 3+ in La 0.7 Sr 0.3 MnO 3 with smaller cation Gd 3+ induced A-site vacancy of the largest Sr 2+ cation with surface segregation of SrO y due to ionic size mismatch, and the induced vacancies reduced migration energy barrier. The operating voltage decreased from 3.5 V to 2.5 V due to a favorable condition for electrochemical migration and redox of oxygen ions. Moreover, surface-segregated SrO y was enhanced with Gd-substitution and the SrO y reduced Schottky-like barrier height and resistive switching ratio from the potential drop and screening effect. The relationship between A-site vacancy generation resulting in surface segregation of SrO y and resistive switching behavior was also investigated by energy resolved x-ray photoelectron spectroscopy, O 1s near edge x-ray absorption spectroscopy, and current voltage measurement.

Original languageEnglish
Article number191604
JournalApplied Physics Letters
Volume104
Issue number19
DOIs
Publication statusPublished - 2014 May 12

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substitutes
cations
x ray spectroscopy
thin films
electric potential
oxygen ions
x ray absorption
electrical measurement
absorption spectroscopy
screening
photoelectron spectroscopy
energy

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

Cite this

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abstract = "This study demonstrated that the resistive switching voltage of perovskite manganite material could be controlled by A-site cation substitution in {"}A{"} MnO 3 perovskite manganite structure. A partial substitution of La 3+ in La 0.7 Sr 0.3 MnO 3 with smaller cation Gd 3+ induced A-site vacancy of the largest Sr 2+ cation with surface segregation of SrO y due to ionic size mismatch, and the induced vacancies reduced migration energy barrier. The operating voltage decreased from 3.5 V to 2.5 V due to a favorable condition for electrochemical migration and redox of oxygen ions. Moreover, surface-segregated SrO y was enhanced with Gd-substitution and the SrO y reduced Schottky-like barrier height and resistive switching ratio from the potential drop and screening effect. The relationship between A-site vacancy generation resulting in surface segregation of SrO y and resistive switching behavior was also investigated by energy resolved x-ray photoelectron spectroscopy, O 1s near edge x-ray absorption spectroscopy, and current voltage measurement.",
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Effect of La 3+ substitution with Gd 3+ on the resistive switching properties of La 0.7 Sr 0.3 MnO 3 thin films . / Lee, Hong Sub; Park, Chang Sun; Park, Hyung-Ho.

In: Applied Physics Letters, Vol. 104, No. 19, 191604, 12.05.2014.

Research output: Contribution to journalArticle

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N2 - This study demonstrated that the resistive switching voltage of perovskite manganite material could be controlled by A-site cation substitution in "A" MnO 3 perovskite manganite structure. A partial substitution of La 3+ in La 0.7 Sr 0.3 MnO 3 with smaller cation Gd 3+ induced A-site vacancy of the largest Sr 2+ cation with surface segregation of SrO y due to ionic size mismatch, and the induced vacancies reduced migration energy barrier. The operating voltage decreased from 3.5 V to 2.5 V due to a favorable condition for electrochemical migration and redox of oxygen ions. Moreover, surface-segregated SrO y was enhanced with Gd-substitution and the SrO y reduced Schottky-like barrier height and resistive switching ratio from the potential drop and screening effect. The relationship between A-site vacancy generation resulting in surface segregation of SrO y and resistive switching behavior was also investigated by energy resolved x-ray photoelectron spectroscopy, O 1s near edge x-ray absorption spectroscopy, and current voltage measurement.

AB - This study demonstrated that the resistive switching voltage of perovskite manganite material could be controlled by A-site cation substitution in "A" MnO 3 perovskite manganite structure. A partial substitution of La 3+ in La 0.7 Sr 0.3 MnO 3 with smaller cation Gd 3+ induced A-site vacancy of the largest Sr 2+ cation with surface segregation of SrO y due to ionic size mismatch, and the induced vacancies reduced migration energy barrier. The operating voltage decreased from 3.5 V to 2.5 V due to a favorable condition for electrochemical migration and redox of oxygen ions. Moreover, surface-segregated SrO y was enhanced with Gd-substitution and the SrO y reduced Schottky-like barrier height and resistive switching ratio from the potential drop and screening effect. The relationship between A-site vacancy generation resulting in surface segregation of SrO y and resistive switching behavior was also investigated by energy resolved x-ray photoelectron spectroscopy, O 1s near edge x-ray absorption spectroscopy, and current voltage measurement.

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