Effect of liquid temperature on thermal stability and crystallization behavior of Ni-based amorphous alloys

J. K. Lee; D. H. Bae; W. T. Kim; D. H. Kim

doi:10.1016/j.msea.2003.10.103

Effect of liquid temperature on thermal stability and crystallization behavior of Ni-based amorphous alloys

J. K. Lee, D. H. Bae, W. T. Kim, D. H. Kim

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The effect of liquid ejection temperature (T_liq) during melt-spinning on the thermal stability and crystallization behavior of amorphous Ni₅₉Zr₂₀Ti₁₆Si_5-xSn_x (x=0,3) alloys has been studied. Glass transition temperature (T_g) and crystallization onset temperature (T_x) of the amorphous Ni₅₉Zr₂₀Ti₁₆Si₅ alloy are not affected by the variation of T_liq. On the other hand, the amorphous Ni₅₉Zr₂₀Ti₁₆Si₂Sn₃ alloy shows different behaviors. T_g is not dependent on T_liq but T_x shifts towards the lower temperature side with decreasing T_liq, resulting in a decrease of the supercooled liquid region (δT_x=T_x-T_g). The effect of T_liq on the thermal properties can be understood by the presence of short-range order clusters, which is related to Ni-Zr atomic pairs in the liquid state.

Original language	English
Pages (from-to)	332-335
Number of pages	4
Journal	Materials Science and Engineering A
Volume	375-377
Issue number	1-2 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.msea.2003.10.103
Publication status	Published - 2004 Jul

Bibliographical note

Funding Information:
This work is supported by the Creative Research Initiatives of the Korean Ministry of Science and Technology.

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/j.msea.2003.10.103

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@article{e958271d5eca4c6892d66946a41be348,

title = "Effect of liquid temperature on thermal stability and crystallization behavior of Ni-based amorphous alloys",

abstract = "The effect of liquid ejection temperature (Tliq) during melt-spinning on the thermal stability and crystallization behavior of amorphous Ni59Zr20Ti16Si5-xSnx (x=0,3) alloys has been studied. Glass transition temperature (Tg) and crystallization onset temperature (Tx) of the amorphous Ni59Zr20Ti16Si5 alloy are not affected by the variation of Tliq. On the other hand, the amorphous Ni59Zr20Ti16Si2Sn3 alloy shows different behaviors. Tg is not dependent on Tliq but Tx shifts towards the lower temperature side with decreasing Tliq, resulting in a decrease of the supercooled liquid region (δTx=Tx-Tg). The effect of Tliq on the thermal properties can be understood by the presence of short-range order clusters, which is related to Ni-Zr atomic pairs in the liquid state.",

author = "Lee, {J. K.} and Bae, {D. H.} and Kim, {W. T.} and Kim, {D. H.}",

note = "Funding Information: This work is supported by the Creative Research Initiatives of the Korean Ministry of Science and Technology.",

year = "2004",

month = jul,

doi = "10.1016/j.msea.2003.10.103",

language = "English",

volume = "375-377",

pages = "332--335",

journal = "Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing",

issn = "0921-5093",

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number = "1-2 SPEC. ISS.",

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TY - JOUR

T1 - Effect of liquid temperature on thermal stability and crystallization behavior of Ni-based amorphous alloys

AU - Lee, J. K.

AU - Bae, D. H.

AU - Kim, W. T.

AU - Kim, D. H.

N1 - Funding Information: This work is supported by the Creative Research Initiatives of the Korean Ministry of Science and Technology.

PY - 2004/7

Y1 - 2004/7

N2 - The effect of liquid ejection temperature (Tliq) during melt-spinning on the thermal stability and crystallization behavior of amorphous Ni59Zr20Ti16Si5-xSnx (x=0,3) alloys has been studied. Glass transition temperature (Tg) and crystallization onset temperature (Tx) of the amorphous Ni59Zr20Ti16Si5 alloy are not affected by the variation of Tliq. On the other hand, the amorphous Ni59Zr20Ti16Si2Sn3 alloy shows different behaviors. Tg is not dependent on Tliq but Tx shifts towards the lower temperature side with decreasing Tliq, resulting in a decrease of the supercooled liquid region (δTx=Tx-Tg). The effect of Tliq on the thermal properties can be understood by the presence of short-range order clusters, which is related to Ni-Zr atomic pairs in the liquid state.

AB - The effect of liquid ejection temperature (Tliq) during melt-spinning on the thermal stability and crystallization behavior of amorphous Ni59Zr20Ti16Si5-xSnx (x=0,3) alloys has been studied. Glass transition temperature (Tg) and crystallization onset temperature (Tx) of the amorphous Ni59Zr20Ti16Si5 alloy are not affected by the variation of Tliq. On the other hand, the amorphous Ni59Zr20Ti16Si2Sn3 alloy shows different behaviors. Tg is not dependent on Tliq but Tx shifts towards the lower temperature side with decreasing Tliq, resulting in a decrease of the supercooled liquid region (δTx=Tx-Tg). The effect of Tliq on the thermal properties can be understood by the presence of short-range order clusters, which is related to Ni-Zr atomic pairs in the liquid state.

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DO - 10.1016/j.msea.2003.10.103

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VL - 375-377

SP - 332

EP - 335

JO - Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing

JF - Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing

SN - 0921-5093

IS - 1-2 SPEC. ISS.

ER -

Effect of liquid temperature on thermal stability and crystallization behavior of Ni-based amorphous alloys

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