Abstract
Partially exfoliated nanocomposite (2) has been synthesized by intercalation of poly(propylene carbonate) (PPC) into commercial clay, Cloisite 20B (PPC/C-20B). Nanocomposite 2 was characterized phiso-chemically and exhibited high thermal, mechanical and anti-water sorption properties as compared to PPC and intercalated nanocomposite (1) of PPC/C- 20B having same amount of clay. TGA results revealed that the thermal decomposition temperature (T d, 50%) of 2 increased significantly, being 40 K and 17 K higher than that of pure PPC and 1, respectively, while DSC measurements indicated that the nano-filler dispersion of 2 increased the glass transition temperature from 21°C to 31°C. Accordingly, 2 showed high elastic modulus, hardness and anti-water absorption capacity. These thermal, mechanical and anti-water absorption improvements are of great importance for the application of PPC as packaging and biomaterials.
| Original language | English |
|---|---|
| Pages (from-to) | 735-743 |
| Number of pages | 9 |
| Journal | Chinese Journal of Polymer Science (English Edition) |
| Volume | 30 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2012 Sep |
Bibliographical note
Funding Information:* This work was financially supported by the National Research Foundation of Korea Grant funded by the Korean Government (MEST) (NRF-2009-C1AAA001-2009-0092926) and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MEST) (No. 2011-0016750). ** Corresponding author: Sher Bahadar Khan, E-mail: sbkhan@kau.edu.sa Haksoo Han, E-mail: hshan@yonsei.ac.kr Received December 21, 2011; Revised March 2, 2012; Accepted March 6, 2012 doi: 10.1007/s10118-012-1168-5
All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)
- Organic Chemistry
- Polymers and Plastics