Effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst for water-gas shift reaction

Hyun Suk Na; Seon Yong Ahn; Jae Oh Shim; Kyung Won Jeon; Hak Min Kim; Yeol Lim Lee; Won Jun Jang; Byong Hun Jeon; Hyun Seog Roh

doi:10.1007/s11814-019-0309-8

Effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst for water-gas shift reaction

Hyun Suk Na, Seon Yong Ahn, Jae Oh Shim, Kyung Won Jeon, Hak Min Kim, Yeol Lim Lee, Won Jun Jang, Byong Hun Jeon, Hyun Seog Roh

Division of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

To investigate the effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst, the pH value and injection rate in the precipitation process were systematically changed, and the water-gas shift reaction was carried out. The Cu-Zn-Al catalyst showed the highest CO conversion when the optimized synthesis parameters (i.e., pH=10-10.5 and injection rate=30 ml/min) were employed. This is mainly due to the enhanced physicochemical properties such as a high Brunauer-Emmett-Teller surface area, small crystallite size, high Cu dispersion, and easier reducibility.

Original language	English
Pages (from-to)	1243-1248
Number of pages	6
Journal	Korean Journal of Chemical Engineering
Volume	36
Issue number	8
DOIs	https://doi.org/10.1007/s11814-019-0309-8
Publication status	Published - 2019 Aug 1

Bibliographical note

Funding Information:
This work was conducted under the framework of the research and development program of the Korea Institute of Energy Research (B7-2424). It was supported (in part) by the Yonsei University Research Fund of 2019.

Publisher Copyright:
© 2019, The Korean Institute of Chemical Engineers.

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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10.1007/s11814-019-0309-8

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title = "Effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst for water-gas shift reaction",

abstract = "To investigate the effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst, the pH value and injection rate in the precipitation process were systematically changed, and the water-gas shift reaction was carried out. The Cu-Zn-Al catalyst showed the highest CO conversion when the optimized synthesis parameters (i.e., pH=10-10.5 and injection rate=30 ml/min) were employed. This is mainly due to the enhanced physicochemical properties such as a high Brunauer-Emmett-Teller surface area, small crystallite size, high Cu dispersion, and easier reducibility.",

author = "Na, {Hyun Suk} and Ahn, {Seon Yong} and Shim, {Jae Oh} and Jeon, {Kyung Won} and Kim, {Hak Min} and Lee, {Yeol Lim} and Jang, {Won Jun} and Jeon, {Byong Hun} and Roh, {Hyun Seog}",

note = "Funding Information: This work was conducted under the framework of the research and development program of the Korea Institute of Energy Research (B7-2424). It was supported (in part) by the Yonsei University Research Fund of 2019. Publisher Copyright: {\textcopyright} 2019, The Korean Institute of Chemical Engineers.",

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doi = "10.1007/s11814-019-0309-8",

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T1 - Effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst for water-gas shift reaction

AU - Na, Hyun Suk

AU - Ahn, Seon Yong

AU - Shim, Jae Oh

AU - Jeon, Kyung Won

AU - Kim, Hak Min

AU - Lee, Yeol Lim

AU - Jang, Won Jun

AU - Jeon, Byong Hun

AU - Roh, Hyun Seog

N1 - Funding Information: This work was conducted under the framework of the research and development program of the Korea Institute of Energy Research (B7-2424). It was supported (in part) by the Yonsei University Research Fund of 2019. Publisher Copyright: © 2019, The Korean Institute of Chemical Engineers.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - To investigate the effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst, the pH value and injection rate in the precipitation process were systematically changed, and the water-gas shift reaction was carried out. The Cu-Zn-Al catalyst showed the highest CO conversion when the optimized synthesis parameters (i.e., pH=10-10.5 and injection rate=30 ml/min) were employed. This is mainly due to the enhanced physicochemical properties such as a high Brunauer-Emmett-Teller surface area, small crystallite size, high Cu dispersion, and easier reducibility.

AB - To investigate the effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst, the pH value and injection rate in the precipitation process were systematically changed, and the water-gas shift reaction was carried out. The Cu-Zn-Al catalyst showed the highest CO conversion when the optimized synthesis parameters (i.e., pH=10-10.5 and injection rate=30 ml/min) were employed. This is mainly due to the enhanced physicochemical properties such as a high Brunauer-Emmett-Teller surface area, small crystallite size, high Cu dispersion, and easier reducibility.

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JF - Korean Journal of Chemical Engineering

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ER -

Effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst for water-gas shift reaction

Abstract

Bibliographical note

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