Effect of reaction solvent on the hydrogenation of isophthalonitrile for meta-xylylendiamine preparation

Sung Wook Row; Tae Young Chae; Kye Sang Yoo; Sang Duek Lee; Do Weon Lee; Yonggun Shul

doi:10.1002/cjce.5450850614

Effect of reaction solvent on the hydrogenation of isophthalonitrile for meta-xylylendiamine preparation

Sung Wook Row, Tae Young Chae, Kye Sang Yoo, Sang Duek Lee, Do Weon Lee, Yonggun Shul

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

This study focused on the effects of reaction solvent on the hydrogenation of isophthalonitrile (IPN) to produce m-Xylylenediamine (MXDA) over Ni-based commercial catalyst. The hydrogenation was carried out using various reaction solvents such as 1-methylimidazole, mesitylene, benzyl ether and isopropanol under various reaction conditions. It was observed that 1-methylimiazole outperformed the other reaction solvent, exhibiting a high MXDA yield and producing a low concentration of undesirable products.

Original language	English
Pages (from-to)	925-928
Number of pages	4
Journal	Canadian Journal of Chemical Engineering
Volume	85
Issue number	6
DOIs	https://doi.org/10.1002/cjce.5450850614
Publication status	Published - 2007 Dec

All Science Journal Classification (ASJC) codes

Chemical Engineering(all)

Access to Document

10.1002/cjce.5450850614

Cite this

@article{93b96fc5a6cd4e80b3abe06822a6a747,

title = "Effect of reaction solvent on the hydrogenation of isophthalonitrile for meta-xylylendiamine preparation",

abstract = "This study focused on the effects of reaction solvent on the hydrogenation of isophthalonitrile (IPN) to produce m-Xylylenediamine (MXDA) over Ni-based commercial catalyst. The hydrogenation was carried out using various reaction solvents such as 1-methylimidazole, mesitylene, benzyl ether and isopropanol under various reaction conditions. It was observed that 1-methylimiazole outperformed the other reaction solvent, exhibiting a high MXDA yield and producing a low concentration of undesirable products.",

author = "Row, {Sung Wook} and Chae, {Tae Young} and Yoo, {Kye Sang} and Lee, {Sang Duek} and Lee, {Do Weon} and Yonggun Shul",

year = "2007",

month = dec,

doi = "10.1002/cjce.5450850614",

language = "English",

volume = "85",

pages = "925--928",

journal = "Canadian Journal of Chemical Engineering",

issn = "0008-4034",

publisher = "Wiley-Liss Inc.",

number = "6",

}

TY - JOUR

T1 - Effect of reaction solvent on the hydrogenation of isophthalonitrile for meta-xylylendiamine preparation

AU - Row, Sung Wook

AU - Chae, Tae Young

AU - Yoo, Kye Sang

AU - Lee, Sang Duek

AU - Lee, Do Weon

AU - Shul, Yonggun

PY - 2007/12

Y1 - 2007/12

N2 - This study focused on the effects of reaction solvent on the hydrogenation of isophthalonitrile (IPN) to produce m-Xylylenediamine (MXDA) over Ni-based commercial catalyst. The hydrogenation was carried out using various reaction solvents such as 1-methylimidazole, mesitylene, benzyl ether and isopropanol under various reaction conditions. It was observed that 1-methylimiazole outperformed the other reaction solvent, exhibiting a high MXDA yield and producing a low concentration of undesirable products.

AB - This study focused on the effects of reaction solvent on the hydrogenation of isophthalonitrile (IPN) to produce m-Xylylenediamine (MXDA) over Ni-based commercial catalyst. The hydrogenation was carried out using various reaction solvents such as 1-methylimidazole, mesitylene, benzyl ether and isopropanol under various reaction conditions. It was observed that 1-methylimiazole outperformed the other reaction solvent, exhibiting a high MXDA yield and producing a low concentration of undesirable products.

UR - http://www.scopus.com/inward/record.url?scp=38349150631&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=38349150631&partnerID=8YFLogxK

U2 - 10.1002/cjce.5450850614

DO - 10.1002/cjce.5450850614

M3 - Article

AN - SCOPUS:38349150631

VL - 85

SP - 925

EP - 928

JO - Canadian Journal of Chemical Engineering

JF - Canadian Journal of Chemical Engineering

SN - 0008-4034

IS - 6

ER -

Effect of reaction solvent on the hydrogenation of isophthalonitrile for meta-xylylendiamine preparation

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this