Effect of selective catalytic reactor on oxidation and enhanced removal of mercury in coal-fired power plants

Deepak Pudasainee, Sung Jun Lee, Sang Hyeob Lee, Jeong Hun Kim, Ha Na Jang, Sung Jin Cho, Yongchil Seo

Research output: Contribution to journalArticle

97 Citations (Scopus)

Abstract

The present study investigated the variation of mercury (Hg) speciation within the air pollution control devices (APCDs) in bituminous coal-fired power plants. The effect of selective catalytic reduction (SCR) system, which is mainly installed for NOx removal, on elemental Hg (Hg0) oxidation and enhancement of Hg removal within APCDs, was studied. Hg speciations in flue gas at the inlet and outlet of each APCDs, such as SCR, cold-side electrostatic precipitator (CS-ESP) and flue gas desulphurization (FGD), were analyzed. Sampling and analysis were carried out according to Ontario Hydro Method (OHM). Overall Hg removal efficiency of APCDs, on average, was about 61% and 47% with and without SCR system, respectively. In the flue gas, Hg was mainly distributed in gaseous (elemental and oxidized) form. The oxidized to elemental Hg partitioning coefficient increased due to oxidation of Hg0 across the SCR system and decreased due to the removal of oxidized Hg (Hg2+) across a wet FGD system. Hg0 oxidation across the SCR system varied from 74% to 7% in tested coal-fired power plants. The comparative study shows that the installation of an SCR system increased Hg removal efficiency and suppressed the reemission of captured Hg0 within a wet FGD system.

Original languageEnglish
Pages (from-to)804-809
Number of pages6
JournalFuel
Volume89
Issue number4
DOIs
Publication statusPublished - 2010 Apr 1

Fingerprint

Selective catalytic reduction
Coal
Mercury
Air pollution control
Power plants
Flue gases
Oxidation
Electrostatic precipitators
Bituminous coal
Sampling

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Organic Chemistry

Cite this

Pudasainee, Deepak ; Lee, Sung Jun ; Lee, Sang Hyeob ; Kim, Jeong Hun ; Jang, Ha Na ; Cho, Sung Jin ; Seo, Yongchil. / Effect of selective catalytic reactor on oxidation and enhanced removal of mercury in coal-fired power plants. In: Fuel. 2010 ; Vol. 89, No. 4. pp. 804-809.
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abstract = "The present study investigated the variation of mercury (Hg) speciation within the air pollution control devices (APCDs) in bituminous coal-fired power plants. The effect of selective catalytic reduction (SCR) system, which is mainly installed for NOx removal, on elemental Hg (Hg0) oxidation and enhancement of Hg removal within APCDs, was studied. Hg speciations in flue gas at the inlet and outlet of each APCDs, such as SCR, cold-side electrostatic precipitator (CS-ESP) and flue gas desulphurization (FGD), were analyzed. Sampling and analysis were carried out according to Ontario Hydro Method (OHM). Overall Hg removal efficiency of APCDs, on average, was about 61{\%} and 47{\%} with and without SCR system, respectively. In the flue gas, Hg was mainly distributed in gaseous (elemental and oxidized) form. The oxidized to elemental Hg partitioning coefficient increased due to oxidation of Hg0 across the SCR system and decreased due to the removal of oxidized Hg (Hg2+) across a wet FGD system. Hg0 oxidation across the SCR system varied from 74{\%} to 7{\%} in tested coal-fired power plants. The comparative study shows that the installation of an SCR system increased Hg removal efficiency and suppressed the reemission of captured Hg0 within a wet FGD system.",
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Effect of selective catalytic reactor on oxidation and enhanced removal of mercury in coal-fired power plants. / Pudasainee, Deepak; Lee, Sung Jun; Lee, Sang Hyeob; Kim, Jeong Hun; Jang, Ha Na; Cho, Sung Jin; Seo, Yongchil.

In: Fuel, Vol. 89, No. 4, 01.04.2010, p. 804-809.

Research output: Contribution to journalArticle

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AU - Lee, Sung Jun

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AU - Cho, Sung Jin

AU - Seo, Yongchil

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