Abstract
The effect of Y addition on the glass forming ability (GFA) of in Fe 70TM(TM=Mn, Mo, Ni)13B17 alloys have been examined in the present study. Substitution of 3-10 at% Fe with Y improves the GFA. Fe70-xMn13B17Yx, (x = 5) and Fe70-xMo13B17Yx (x = 3) alloys exhibit high Trg (= Tg/Tl) (>0.55) and γ (= Tx/[Tl + Tg]) (>0.37) values enabling fabrication of 1 mm diameter bulk metallic glass. The GFA improves when addition of Y decreases the melting temperature, and, at the same time, increases the crystallization onset temperature. Extended Kissinger analysis of the DSC data indicates that a kinetic boundary condition for the formation of the amorphous phase widens by addition of Y.
| Original language | English |
|---|---|
| Pages (from-to) | 2770-2775 |
| Number of pages | 6 |
| Journal | Materials Transactions |
| Volume | 45 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2004 Jan 1 |
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All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
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Effect of yttrium addition on thermal stability and glass forming ability in Fe-TM (Mn, Mo, Ni)-b ternary alloys. / Kim, Ji Hun; Park, Joon Sik; Fleury, Eric; Kim, Won Tae; Kim, Do Hyang.
In: Materials Transactions, Vol. 45, No. 8, 01.01.2004, p. 2770-2775.Research output: Contribution to journal › Article
TY - JOUR
T1 - Effect of yttrium addition on thermal stability and glass forming ability in Fe-TM (Mn, Mo, Ni)-b ternary alloys
AU - Kim, Ji Hun
AU - Park, Joon Sik
AU - Fleury, Eric
AU - Kim, Won Tae
AU - Kim, Do Hyang
PY - 2004/1/1
Y1 - 2004/1/1
N2 - The effect of Y addition on the glass forming ability (GFA) of in Fe 70TM(TM=Mn, Mo, Ni)13B17 alloys have been examined in the present study. Substitution of 3-10 at% Fe with Y improves the GFA. Fe70-xMn13B17Yx, (x = 5) and Fe70-xMo13B17Yx (x = 3) alloys exhibit high Trg (= Tg/Tl) (>0.55) and γ (= Tx/[Tl + Tg]) (>0.37) values enabling fabrication of 1 mm diameter bulk metallic glass. The GFA improves when addition of Y decreases the melting temperature, and, at the same time, increases the crystallization onset temperature. Extended Kissinger analysis of the DSC data indicates that a kinetic boundary condition for the formation of the amorphous phase widens by addition of Y.
AB - The effect of Y addition on the glass forming ability (GFA) of in Fe 70TM(TM=Mn, Mo, Ni)13B17 alloys have been examined in the present study. Substitution of 3-10 at% Fe with Y improves the GFA. Fe70-xMn13B17Yx, (x = 5) and Fe70-xMo13B17Yx (x = 3) alloys exhibit high Trg (= Tg/Tl) (>0.55) and γ (= Tx/[Tl + Tg]) (>0.37) values enabling fabrication of 1 mm diameter bulk metallic glass. The GFA improves when addition of Y decreases the melting temperature, and, at the same time, increases the crystallization onset temperature. Extended Kissinger analysis of the DSC data indicates that a kinetic boundary condition for the formation of the amorphous phase widens by addition of Y.
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U2 - 10.2320/matertrans.45.2770
DO - 10.2320/matertrans.45.2770
M3 - Article
VL - 45
SP - 2770
EP - 2775
JO - Materials Transactions
JF - Materials Transactions
SN - 0916-1821
IS - 8
ER -