Effects of high polymer concentration for alignment of liquid crystal on rubbed polyimide surfaces containing trifluoromethyl moieties

Dae-Shik Seo, Shunsuke Kobayashi

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The effects of high polymer concentration for alignment of liquid crystal (LC) on rubbed polyimide (Pi) surfaces containing trifluoromethyl moieties have been successfully evaluated by measuring the pretilt angle, surface ordering, and polar anchoring strength. The pretilt angle of 5CB is increased by combination of steric interaction between the LCs and the substrate surfaces on rubbed special PI and low surface energy due to rich fluorine atoms on surfaces was demonstrated. The surface order parameter of 5CB for high polymer concentration is small compared to low polymer concentration. We suggest that the surface order parameter is decreased by low surface energy caused by rich fluorine atoms. The polar anchoring strength of 5CB near the clearing temperature for high polymer concentration is very weak compared to low polymer concentration. Finally, we suggest that the pretilt angle, surface ordering, and polar anchoring strength in 5CB strongly depend on character of polymer on surfaces.

Original languageEnglish
Pages (from-to)L786-L788
JournalJapanese Journal of Applied Physics
Volume34
Issue number6
DOIs
Publication statusPublished - 1995 Jun 1

Fingerprint

high polymers
polyimides
Polyimides
Liquid crystals
liquid crystals
alignment
Polymers
Fluorine
Interfacial energy
surface energy
fluorine
polymers
Atoms
clearing
atoms
Substrates

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

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abstract = "The effects of high polymer concentration for alignment of liquid crystal (LC) on rubbed polyimide (Pi) surfaces containing trifluoromethyl moieties have been successfully evaluated by measuring the pretilt angle, surface ordering, and polar anchoring strength. The pretilt angle of 5CB is increased by combination of steric interaction between the LCs and the substrate surfaces on rubbed special PI and low surface energy due to rich fluorine atoms on surfaces was demonstrated. The surface order parameter of 5CB for high polymer concentration is small compared to low polymer concentration. We suggest that the surface order parameter is decreased by low surface energy caused by rich fluorine atoms. The polar anchoring strength of 5CB near the clearing temperature for high polymer concentration is very weak compared to low polymer concentration. Finally, we suggest that the pretilt angle, surface ordering, and polar anchoring strength in 5CB strongly depend on character of polymer on surfaces.",
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Effects of high polymer concentration for alignment of liquid crystal on rubbed polyimide surfaces containing trifluoromethyl moieties. / Seo, Dae-Shik; Kobayashi, Shunsuke.

In: Japanese Journal of Applied Physics, Vol. 34, No. 6, 01.06.1995, p. L786-L788.

Research output: Contribution to journalArticle

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