Effects of Ionomer Carbon Ratio and Ionomer Dispersity on the Performance and Durability of MEAs

M. R. Lee, H. Y. Lee, S. D. Yim, C. S. Kim, Y. G. Shul, A. Kucernak, D. Shin

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Membrane-electrode assemblies (MEAs) are fabricated using different catalysts and ionomers, in order to investigate the effects of these factors on the performance and stability of the polymer electrolyte membrane fuel cell (PEMFC). Platinum catalysts with different degrees of graphitization in the carbon support (less graphitized: Tanaka, more graphitized: RTX) are used. Perfluorosulfonic acid polymer-based ionomers with water-based or organic solvent-based solvents are also prepared as binders for the electrode. The optimum composition of catalyst and ionomer is identified based on the results of cyclic voltammetry, electrochemical impedance spectroscopy, single cell performance, and long-term durability tests. Tanaka catalyst and water-based ionomer show the best performance and durability. In addition, the ionomer to carbon (I/C) weight ratio affects the fuel cell performance, and the optimum value is I/C = 1 for both water-based and organic solvent-based ionomers.

Original languageEnglish
Pages (from-to)129-136
Number of pages8
JournalFuel Cells
Volume18
Issue number2
DOIs
Publication statusPublished - 2018 Apr

Bibliographical note

Funding Information:
This work was supported by the International Collaborative Energy Technology R&D Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP), under financial resources from the Ministry of Trade, Industry & Energy, Republic of Korea (No. 20148520120160) and the framework of the Research and Development Program of the Korea Institute of Energy Research (KIER) (B8-2422).

Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology

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