Efficient waste to energy conversion based on co-ceo2 catalyzed water-gas shift reaction

Kyoung Jin Kim, Yeol Lim Lee, Hyun Suk Na, Seon Yong Ahn, Jae Oh Shim, Byong Hun Jeon, Hyun Seog Roh

Research output: Contribution to journalArticle

Abstract

Waste to energy technology is attracting attention to overcome the upcoming environmental and energy issues. One of the key-steps is the water-gas shift (WGS) reaction, which can convert the waste-derived synthesis gas (H2 and CO) to pure hydrogen. Co–CeO2 catalysts were synthesized by the different methods to derive the optimal synthetic method and to investigate the effect of the preparation method on the physicochemical characteristics of Co–CeO2 catalysts in the high-temperature water-gas shift (HTS) reaction. The Co–CeO2 catalyst synthesized by the sol-gel method featured a strong metal to support interaction and the largest number of oxygen vacancies compared to other catalysts, which affects the catalytic activity. As a result, the Co–CeO2 catalyst synthesized by the sol-gel method exhibited the highest WGS activity among the prepared catalysts, even in severe conditions (high CO concentration: ~38% in dry basis and high gas hourly space velocity: 143,000 h−1 ).

Original languageEnglish
Article number420
JournalCatalysts
Volume10
Issue number4
DOIs
Publication statusPublished - 2020 Apr

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry

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