Electrocatalytic Oxygen Reduction by Dopant-free, Porous Graphene Aerogel

Woojun Choi, Uday Pratap Azad, Jai Pil Choi, Dongil Lee

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Porous graphene aerogel (GA) was prepared by the hydrothermal reduction of graphene oxide (GO). The prepared GA was characterized with the various analytical techniques. Its morphological and electrochemical properties were investigated and compared with those of GO and electrochemically reduced graphene oxide (erGO). Three glassy carbon (GC) electrodes modified with GO, erGO, and GA were employed to study the electrocatalytic oxygen reduction reaction (ORR). The influence of GA porosity on the kinetic parameters of the ORR was also investigated. Whereas two-electron transfer ORR was observed at the erGO- and GO-modified electrodes, the GA-modified electrode exhibited drastically enhanced electrocatalytic ORR activity. The remarkable electrocatalytic activity of GA can be attributed to the unique porous effect of GA. The porous GA offers confined spaces for ORR that would drastically increase the residence time of oxygen and thus enhance the contact frequency for the reduction of oxygen. Additional rotating disk electrode voltammetry corroborates that the porous GA facilitates efficient ORR.

Original languageEnglish
Pages (from-to)1472-1478
Number of pages7
JournalElectroanalysis
Volume30
Issue number7
DOIs
Publication statusPublished - 2018 Jul 1

Fingerprint

Aerogels
Graphite
Graphene
Doping (additives)
Oxygen
Oxides
Electrodes
Glassy carbon
Rotating disks
Voltammetry
Electrochemical properties
Kinetic parameters

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Electrochemistry

Cite this

Choi, Woojun ; Azad, Uday Pratap ; Choi, Jai Pil ; Lee, Dongil. / Electrocatalytic Oxygen Reduction by Dopant-free, Porous Graphene Aerogel. In: Electroanalysis. 2018 ; Vol. 30, No. 7. pp. 1472-1478.
@article{bff1e5b432e743b2882a1ea96ed2eeaa,
title = "Electrocatalytic Oxygen Reduction by Dopant-free, Porous Graphene Aerogel",
abstract = "Porous graphene aerogel (GA) was prepared by the hydrothermal reduction of graphene oxide (GO). The prepared GA was characterized with the various analytical techniques. Its morphological and electrochemical properties were investigated and compared with those of GO and electrochemically reduced graphene oxide (erGO). Three glassy carbon (GC) electrodes modified with GO, erGO, and GA were employed to study the electrocatalytic oxygen reduction reaction (ORR). The influence of GA porosity on the kinetic parameters of the ORR was also investigated. Whereas two-electron transfer ORR was observed at the erGO- and GO-modified electrodes, the GA-modified electrode exhibited drastically enhanced electrocatalytic ORR activity. The remarkable electrocatalytic activity of GA can be attributed to the unique porous effect of GA. The porous GA offers confined spaces for ORR that would drastically increase the residence time of oxygen and thus enhance the contact frequency for the reduction of oxygen. Additional rotating disk electrode voltammetry corroborates that the porous GA facilitates efficient ORR.",
author = "Woojun Choi and Azad, {Uday Pratap} and Choi, {Jai Pil} and Dongil Lee",
year = "2018",
month = "7",
day = "1",
doi = "10.1002/elan.201800089",
language = "English",
volume = "30",
pages = "1472--1478",
journal = "Macromolecular Chemistry and Physics",
issn = "1040-0397",
publisher = "Wiley-VCH Verlag",
number = "7",

}

Electrocatalytic Oxygen Reduction by Dopant-free, Porous Graphene Aerogel. / Choi, Woojun; Azad, Uday Pratap; Choi, Jai Pil; Lee, Dongil.

In: Electroanalysis, Vol. 30, No. 7, 01.07.2018, p. 1472-1478.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Electrocatalytic Oxygen Reduction by Dopant-free, Porous Graphene Aerogel

AU - Choi, Woojun

AU - Azad, Uday Pratap

AU - Choi, Jai Pil

AU - Lee, Dongil

PY - 2018/7/1

Y1 - 2018/7/1

N2 - Porous graphene aerogel (GA) was prepared by the hydrothermal reduction of graphene oxide (GO). The prepared GA was characterized with the various analytical techniques. Its morphological and electrochemical properties were investigated and compared with those of GO and electrochemically reduced graphene oxide (erGO). Three glassy carbon (GC) electrodes modified with GO, erGO, and GA were employed to study the electrocatalytic oxygen reduction reaction (ORR). The influence of GA porosity on the kinetic parameters of the ORR was also investigated. Whereas two-electron transfer ORR was observed at the erGO- and GO-modified electrodes, the GA-modified electrode exhibited drastically enhanced electrocatalytic ORR activity. The remarkable electrocatalytic activity of GA can be attributed to the unique porous effect of GA. The porous GA offers confined spaces for ORR that would drastically increase the residence time of oxygen and thus enhance the contact frequency for the reduction of oxygen. Additional rotating disk electrode voltammetry corroborates that the porous GA facilitates efficient ORR.

AB - Porous graphene aerogel (GA) was prepared by the hydrothermal reduction of graphene oxide (GO). The prepared GA was characterized with the various analytical techniques. Its morphological and electrochemical properties were investigated and compared with those of GO and electrochemically reduced graphene oxide (erGO). Three glassy carbon (GC) electrodes modified with GO, erGO, and GA were employed to study the electrocatalytic oxygen reduction reaction (ORR). The influence of GA porosity on the kinetic parameters of the ORR was also investigated. Whereas two-electron transfer ORR was observed at the erGO- and GO-modified electrodes, the GA-modified electrode exhibited drastically enhanced electrocatalytic ORR activity. The remarkable electrocatalytic activity of GA can be attributed to the unique porous effect of GA. The porous GA offers confined spaces for ORR that would drastically increase the residence time of oxygen and thus enhance the contact frequency for the reduction of oxygen. Additional rotating disk electrode voltammetry corroborates that the porous GA facilitates efficient ORR.

UR - http://www.scopus.com/inward/record.url?scp=85045380213&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85045380213&partnerID=8YFLogxK

U2 - 10.1002/elan.201800089

DO - 10.1002/elan.201800089

M3 - Article

AN - SCOPUS:85045380213

VL - 30

SP - 1472

EP - 1478

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1040-0397

IS - 7

ER -