Electrochemical determination of bisphenol a at carbon nanotube-doped titania-nafion composite modified electrode

Byung Kun Kim, Ji Yeon Kim, Dong Hwan Kim, Han Nim Choi, Wonyong Lee

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A highly sensitive electrochemical detection method for bisphenol A (BPA) has been developed by using multi-walled carbon nanotube (CNT)-doped titania-Nafion composite modified glassy carbon (GC) electrode. The CNT-titania-Nafion/GC electrode exhibited excellent electrocatalytic activity towards BPA. Therefore, the CNT-titania-Nafion/GC electrode showed improved voltammetric responses for BPA compared to that obtained with bare GC electrode. In addition, cetyltrimethylammonium bromide (CTAB), a cationic surfactant, was added into the BPA sample solution in order to accumulate BPA through hydrophobic interaction between CTAB and BPA. The CNT-titania-Nafion/GC electrode gave a linear response (r2 = 0.999) for BPA from 1.0 × 10-8 M to 5.0 × 10-6 M with a detection limit of 9.0 × 10-10 M (S/N = 3). The modified electrode showed good selectivity against interfering species and also exhibited good reproducibility. The present electrochemical sensor based on the CNT-titania-Nafion/GC electrode was applied to the determination of BPA in food package samples.

Original languageEnglish
Pages (from-to)1065-1069
Number of pages5
JournalBulletin of the Korean Chemical Society
Volume34
Issue number4
DOIs
Publication statusPublished - 2013 Apr 20

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Carbon Nanotubes
Glassy carbon
Electrodes
Composite materials
Electrochemical sensors
titanium dioxide
perfluorosulfonic acid
bisphenol A
Cationic surfactants

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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title = "Electrochemical determination of bisphenol a at carbon nanotube-doped titania-nafion composite modified electrode",
abstract = "A highly sensitive electrochemical detection method for bisphenol A (BPA) has been developed by using multi-walled carbon nanotube (CNT)-doped titania-Nafion composite modified glassy carbon (GC) electrode. The CNT-titania-Nafion/GC electrode exhibited excellent electrocatalytic activity towards BPA. Therefore, the CNT-titania-Nafion/GC electrode showed improved voltammetric responses for BPA compared to that obtained with bare GC electrode. In addition, cetyltrimethylammonium bromide (CTAB), a cationic surfactant, was added into the BPA sample solution in order to accumulate BPA through hydrophobic interaction between CTAB and BPA. The CNT-titania-Nafion/GC electrode gave a linear response (r2 = 0.999) for BPA from 1.0 × 10-8 M to 5.0 × 10-6 M with a detection limit of 9.0 × 10-10 M (S/N = 3). The modified electrode showed good selectivity against interfering species and also exhibited good reproducibility. The present electrochemical sensor based on the CNT-titania-Nafion/GC electrode was applied to the determination of BPA in food package samples.",
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Electrochemical determination of bisphenol a at carbon nanotube-doped titania-nafion composite modified electrode. / Kim, Byung Kun; Kim, Ji Yeon; Kim, Dong Hwan; Choi, Han Nim; Lee, Wonyong.

In: Bulletin of the Korean Chemical Society, Vol. 34, No. 4, 20.04.2013, p. 1065-1069.

Research output: Contribution to journalArticle

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AU - Kim, Ji Yeon

AU - Kim, Dong Hwan

AU - Choi, Han Nim

AU - Lee, Wonyong

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