Electrochemical quartz crystal microbalance study of the self-assembled multilayered poly(aniline N-butansulfonate) film

Yongku Kang, Eunkyoung Kim, Changjin Lee

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Electrochemically active multilayers of self doped polyaniline films were prepared by the ionic interaction between poly(aniline N-butanesulfonate) (PANBUS) and polyethylene inline. Kinetic constant and free energy of the PANBUS adsorption were calculated to be 2.3/M·sec and -5.4 kcal/mole, respectively from the analysis of QCM. The prepared film showed the characteristic cyclic voltammogram of polyaniline and EQCM study of the multilayered film indicated that the mass change during oxidation and reduction was independent on the cations and anions of the used electrolytes.

Original languageEnglish
Pages (from-to)87-90
Number of pages4
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume371
DOIs
Publication statusPublished - 2001 Jan 1

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Quartz crystal microbalances
Aniline
aniline
quartz crystals
microbalances
Polyaniline
Polyethylene
Electrolytes
Free energy
Anions
Cations
Polyethylenes
polyethylenes
Multilayers
Negative ions
Positive ions
free energy
electrolytes
anions
Adsorption

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

Cite this

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abstract = "Electrochemically active multilayers of self doped polyaniline films were prepared by the ionic interaction between poly(aniline N-butanesulfonate) (PANBUS) and polyethylene inline. Kinetic constant and free energy of the PANBUS adsorption were calculated to be 2.3/M·sec and -5.4 kcal/mole, respectively from the analysis of QCM. The prepared film showed the characteristic cyclic voltammogram of polyaniline and EQCM study of the multilayered film indicated that the mass change during oxidation and reduction was independent on the cations and anions of the used electrolytes.",
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T1 - Electrochemical quartz crystal microbalance study of the self-assembled multilayered poly(aniline N-butansulfonate) film

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N2 - Electrochemically active multilayers of self doped polyaniline films were prepared by the ionic interaction between poly(aniline N-butanesulfonate) (PANBUS) and polyethylene inline. Kinetic constant and free energy of the PANBUS adsorption were calculated to be 2.3/M·sec and -5.4 kcal/mole, respectively from the analysis of QCM. The prepared film showed the characteristic cyclic voltammogram of polyaniline and EQCM study of the multilayered film indicated that the mass change during oxidation and reduction was independent on the cations and anions of the used electrolytes.

AB - Electrochemically active multilayers of self doped polyaniline films were prepared by the ionic interaction between poly(aniline N-butanesulfonate) (PANBUS) and polyethylene inline. Kinetic constant and free energy of the PANBUS adsorption were calculated to be 2.3/M·sec and -5.4 kcal/mole, respectively from the analysis of QCM. The prepared film showed the characteristic cyclic voltammogram of polyaniline and EQCM study of the multilayered film indicated that the mass change during oxidation and reduction was independent on the cations and anions of the used electrolytes.

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