Electrochemical synthesis of a thiophene-containing cyclo[9]pyrrole

Thanh Tuan Bui, Adriana Iordache, Zhongrui Chen, Vladimir V. Roznyatovskiy, Eric Saint-Aman, Jong Min Lim, Byung Sun Lee, Sudip Ghosh, Jean Claude Moutet, Jonathan L. Sessler, Dongho Kim, Christophe Bucher

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α'-positions, is the largest cyclo[n]pyrrole derivative reported to date (see figure).

Original languageEnglish
Pages (from-to)5853-5859
Number of pages7
JournalChemistry - A European Journal
Volume18
Issue number19
DOIs
Publication statusPublished - 2012 May 7

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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