Electrogenerated chemiluminescence ethanol biosensor based on carbon nanotube-titania-Nafion composite film

Nim Choi Han, Hyun Yoon Sook, Young Ku Lyu, Won Yong Lee

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Mesoporous titania-Nafion composite doped with carbon nanotube (CNT) has been used for the immobilization of tris(2,2′-bipyridyl)ruthenium(II) (Ru(bpy)32+) and alcohol dehydrogenase on an electrode surface to yield a highly sensitive and stable electrogenerated chemiluminescence (ECL) ethanol biosensor. The presence of CNT in the composite film increases not only the sensitivity of the ECL biosensor but also the long-term stability of the biosensor. The present biosensor responds linearly to ethanol in the wide concentration ranges from 1.0 × 10-5 M to 1.0 × 10-1 M with a detection limit of 5.0 × 10 -6 M (S/N = 3). The present ECL ethanol biosensor exhibited higher ECL response compared to that obtained with the ECL biosensor based on the corresponding composite without CNT. The present CNT-based ECL biosensor showed good long-term stability with 75% of its initial activity retained after 2 weeks of storage in 50 mM phosphate buffer at pH 7.0.

Original languageEnglish
Pages (from-to)459-465
Number of pages7
JournalElectroanalysis
Volume19
Issue number4
DOIs
Publication statusPublished - 2007 Feb 1

Fingerprint

Carbon Nanotubes
Chemiluminescence
Composite films
Biosensors
Carbon nanotubes
Ethanol
Titanium
2,2'-Dipyridyl
Ruthenium
Alcohol Dehydrogenase
Composite materials
titanium dioxide
perfluorosulfonic acid
Buffers
Phosphates
Alcohols
Electrodes

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Electrochemistry

Cite this

Han, Nim Choi ; Sook, Hyun Yoon ; Lyu, Young Ku ; Lee, Won Yong. / Electrogenerated chemiluminescence ethanol biosensor based on carbon nanotube-titania-Nafion composite film. In: Electroanalysis. 2007 ; Vol. 19, No. 4. pp. 459-465.
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Electrogenerated chemiluminescence ethanol biosensor based on carbon nanotube-titania-Nafion composite film. / Han, Nim Choi; Sook, Hyun Yoon; Lyu, Young Ku; Lee, Won Yong.

In: Electroanalysis, Vol. 19, No. 4, 01.02.2007, p. 459-465.

Research output: Contribution to journalArticle

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