Electrosorption of uranium ions on activated carbon fibers

Chong Hun Jung, Hye Young Lee, Jei Kwon Moon, Hui Jun Won, Yong Gun Shul

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

A study on the electrosorption of uranium (U(VI)) ions onto a porous activated carbon fiber was performed to treat lagoon sludge containing 100 mg/L uranium and high concentration of chemical salts composed 3.8% NaNO3, 19.8% NH4NO3, 1.9% Ca(NO3)2. The applied negative potential increased the adsorption kinetics and capacity in comparison to the open-circuit potential adsorption for uranium ions. When applying potential at -0.9 V (vs. Ag/AgCl) and pH 4, above 99% of the uranium is selectively removed from the 100 mg/L influent by electrosorption, and the cumulative amount of uranium for 50 h is about 600 mguranium/g ACF. The high selectivity of elctrosorption process for uranium was probably caused by the difference of charge density of cations. More than 99% of adsorbed uranium ions was desorbed at a potential of +1.2 V and pH 3. The electrosorption of uranium onto the porous activated carbon fiber electrode is due to an ion exchange type reaction between the uranium ions and surface acid groups on carbon surface. Cyclic electrosorption test consisting of adsorption and desorption step shows that the activated carbon fiber electrode is easily regenerated in situ, indicating it is a reversible process.

Original languageEnglish
Pages (from-to)833-839
Number of pages7
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume287
Issue number3
DOIs
Publication statusPublished - 2011 Mar 1

Fingerprint

Uranium
Activated carbon
Carbon fibers
Ions
Adsorption
Electrodes
carbon fiber
Ion Exchange
Sewage
Charge density
Cations
Desorption
Ion exchange
Carbon
Salts
Positive ions
Kinetics
Acids
Networks (circuits)

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

Cite this

Jung, Chong Hun ; Lee, Hye Young ; Moon, Jei Kwon ; Won, Hui Jun ; Shul, Yong Gun. / Electrosorption of uranium ions on activated carbon fibers. In: Journal of Radioanalytical and Nuclear Chemistry. 2011 ; Vol. 287, No. 3. pp. 833-839.
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Electrosorption of uranium ions on activated carbon fibers. / Jung, Chong Hun; Lee, Hye Young; Moon, Jei Kwon; Won, Hui Jun; Shul, Yong Gun.

In: Journal of Radioanalytical and Nuclear Chemistry, Vol. 287, No. 3, 01.03.2011, p. 833-839.

Research output: Contribution to journalArticle

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