Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window

Nils Huse, Benjamin E. Van Kuiken, Hana Cho, Matthew L. Strader, Tae Kyu Kim, Munira Khalil, Robert W. Schoenlein

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.

Original languageEnglish
Title of host publication18th International Conference on Ultrafast Phenomena, UP 2012
DOIs
Publication statusPublished - 2013 Apr 5
Event18th International Conference on Ultrafast Phenomena, UP 2012 - Lausanne, Switzerland
Duration: 2012 Jul 82012 Jul 13

Publication series

NameEPJ Web of Conferences
Volume41
ISSN (Print)2101-6275
ISSN (Electronic)2100-014X

Conference

Conference18th International Conference on Ultrafast Phenomena, UP 2012
CountrySwitzerland
CityLausanne
Period12/7/812/7/13

Fingerprint

crossovers
aqueous solutions
nitrogen
water
spectroscopy
x rays

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

Huse, N., Van Kuiken, B. E., Cho, H., Strader, M. L., Kim, T. K., Khalil, M., & Schoenlein, R. W. (2013). Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. In 18th International Conference on Ultrafast Phenomena, UP 2012 [05037] (EPJ Web of Conferences; Vol. 41). https://doi.org/10.1051/epjconf/20134105037
Huse, Nils ; Van Kuiken, Benjamin E. ; Cho, Hana ; Strader, Matthew L. ; Kim, Tae Kyu ; Khalil, Munira ; Schoenlein, Robert W. / Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. 18th International Conference on Ultrafast Phenomena, UP 2012. 2013. (EPJ Web of Conferences).
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abstract = "We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.",
author = "Nils Huse and {Van Kuiken}, {Benjamin E.} and Hana Cho and Strader, {Matthew L.} and Kim, {Tae Kyu} and Munira Khalil and Schoenlein, {Robert W.}",
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Huse, N, Van Kuiken, BE, Cho, H, Strader, ML, Kim, TK, Khalil, M & Schoenlein, RW 2013, Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. in 18th International Conference on Ultrafast Phenomena, UP 2012., 05037, EPJ Web of Conferences, vol. 41, 18th International Conference on Ultrafast Phenomena, UP 2012, Lausanne, Switzerland, 12/7/8. https://doi.org/10.1051/epjconf/20134105037

Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. / Huse, Nils; Van Kuiken, Benjamin E.; Cho, Hana; Strader, Matthew L.; Kim, Tae Kyu; Khalil, Munira; Schoenlein, Robert W.

18th International Conference on Ultrafast Phenomena, UP 2012. 2013. 05037 (EPJ Web of Conferences; Vol. 41).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Huse N, Van Kuiken BE, Cho H, Strader ML, Kim TK, Khalil M et al. Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. In 18th International Conference on Ultrafast Phenomena, UP 2012. 2013. 05037. (EPJ Web of Conferences). https://doi.org/10.1051/epjconf/20134105037