Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window

Nils Huse; Benjamin E. Van Kuiken; Hana Cho; Matthew L. Strader; Tae Kyu Kim; Munira Khalil; Robert W. Schoenlein

doi:10.1051/epjconf/20134105037

Elucidating charge delocalization in the high-spin state of aqueous Fe ^II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window

Nils Huse, Benjamin E. Van Kuiken, Hana Cho, Matthew L. Strader, Tae Kyu Kim, Munira Khalil, Robert W. Schoenlein

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.

Original language	English
Title of host publication	18th International Conference on Ultrafast Phenomena, UP 2012
DOIs	https://doi.org/10.1051/epjconf/20134105037
Publication status	Published - 2013
Event	18th International Conference on Ultrafast Phenomena, UP 2012 - Lausanne, Switzerland Duration: 2012 Jul 8 → 2012 Jul 13

Publication series

Name	EPJ Web of Conferences
Volume	41
ISSN (Print)	2101-6275
ISSN (Electronic)	2100-014X

Conference

Conference	18th International Conference on Ultrafast Phenomena, UP 2012
Country/Territory	Switzerland
City	Lausanne
Period	12/7/8 → 12/7/13

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)

Access to Document

10.1051/epjconf/20134105037

Cite this

Huse, N., Van Kuiken, B. E., Cho, H., Strader, M. L., Kim, T. K., Khalil, M., & Schoenlein, R. W. (2013). Elucidating charge delocalization in the high-spin state of aqueous Fe ^II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. In 18th International Conference on Ultrafast Phenomena, UP 2012 [05037] (EPJ Web of Conferences; Vol. 41). https://doi.org/10.1051/epjconf/20134105037

@inproceedings{cdaf278766cc48f9b3ea58ac1610f5b0,

title = "Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window",

abstract = "We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.",

author = "Nils Huse and {Van Kuiken}, {Benjamin E.} and Hana Cho and Strader, {Matthew L.} and Kim, {Tae Kyu} and Munira Khalil and Schoenlein, {Robert W.}",

year = "2013",

doi = "10.1051/epjconf/20134105037",

language = "English",

isbn = "9782759809561",

series = "EPJ Web of Conferences",

booktitle = "18th International Conference on Ultrafast Phenomena, UP 2012",

note = "18th International Conference on Ultrafast Phenomena, UP 2012 ; Conference date: 08-07-2012 Through 13-07-2012",

}

Huse, N, Van Kuiken, BE, Cho, H, Strader, ML, Kim, TK, Khalil, M & Schoenlein, RW 2013, Elucidating charge delocalization in the high-spin state of aqueous Fe ^II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. in 18th International Conference on Ultrafast Phenomena, UP 2012., 05037, EPJ Web of Conferences, vol. 41, 18th International Conference on Ultrafast Phenomena, UP 2012, Lausanne, Switzerland, 12/7/8. https://doi.org/10.1051/epjconf/20134105037

Elucidating charge delocalization in the high-spin state of aqueous Fe ^II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window. / Huse, Nils; Van Kuiken, Benjamin E.; Cho, Hana et al.

18th International Conference on Ultrafast Phenomena, UP 2012. 2013. 05037 (EPJ Web of Conferences; Vol. 41).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Elucidating charge delocalization in the high-spin state of aqueous Fe II spin-crossover compounds via time-resolved spectroscopy in the x-ray water window

AU - Huse, Nils

AU - Van Kuiken, Benjamin E.

AU - Cho, Hana

AU - Strader, Matthew L.

AU - Kim, Tae Kyu

AU - Khalil, Munira

AU - Schoenlein, Robert W.

PY - 2013

Y1 - 2013

N2 - We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.

AB - We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.

UR - http://www.scopus.com/inward/record.url?scp=84875662787&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84875662787&partnerID=8YFLogxK

U2 - 10.1051/epjconf/20134105037

DO - 10.1051/epjconf/20134105037

M3 - Conference contribution

AN - SCOPUS:84875662787

SN - 9782759809561

T3 - EPJ Web of Conferences

BT - 18th International Conference on Ultrafast Phenomena, UP 2012

T2 - 18th International Conference on Ultrafast Phenomena, UP 2012

Y2 - 8 July 2012 through 13 July 2012

ER -