Enabling nanotechnology with self assembled block copolymer patterns

Cheolmin Park, Jongseung Yoon, Edwin L. Thomas

Research output: Contribution to journalReview article

1256 Citations (Scopus)

Abstract

Block copolymers (BCPs) have received great attention for the past 40 years but only within the past decade have they been seriously considered for nanotechnological applications. Their applicability to nanotechnology stems from the scale of the microdomains and the convenient tunability of size, shape, and periodicity afforded by changing their molecular parameters. The use of the tensorial physical properties of BCPs in such areas as transport, mechanical, electrical, and optical properties will provide substantial benefits in the future. In this review article, we first focus on the current efforts to utilize BCPs in nanotechnologies including nanostructured membranes, BCP templates for nanoparticle synthesis, photonic crystals, and high-density information storage media. In order to realize these applications, control over microdomain spatial and orientational order is paramount. This article reviews various methods to control BCP microdomain structures in the bulk state as well as in thin films. A variety of biases such as mechanical flow fields, electric fields, temperature gradients, and surface interactions can manipulate the microstructures of BCPs. A particular emphasis is made on two approaches, epitaxy and graphoepitaxy, and their combinations. Manipulation of BCP microdomain structures employing multiple external fields promises realization of many potential nanotechnological applications.

Original languageEnglish
Pages (from-to)6725-6760
Number of pages36
JournalPolymer
Volume44
Issue number22
DOIs
Publication statusPublished - 2003 Oct 3

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Nanotechnology
Block copolymers
Photonic crystals
Epitaxial growth
Transport properties
Thermal gradients
Flow fields
Electric properties
Optical properties
Physical properties
Electric fields
Nanoparticles
Membranes
Data storage equipment
Thin films
Mechanical properties
Microstructure

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Park, Cheolmin ; Yoon, Jongseung ; Thomas, Edwin L. / Enabling nanotechnology with self assembled block copolymer patterns. In: Polymer. 2003 ; Vol. 44, No. 22. pp. 6725-6760.
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Enabling nanotechnology with self assembled block copolymer patterns. / Park, Cheolmin; Yoon, Jongseung; Thomas, Edwin L.

In: Polymer, Vol. 44, No. 22, 03.10.2003, p. 6725-6760.

Research output: Contribution to journalReview article

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