Enantioselective radical addition reactions to the C=N bond utilizing chiral quaternary ammonium salts of hypophosphorous acid in aqueous media

Dae Hyan Cho, Doo Ok Jang

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

An enantioselective addition of alkyl radicals to glyoxylate oxime ether mediated by Cinchona alkaloid derived chiral ammonium salts of hypophosphorous acid, QP and QDP, has been developed.

Original languageEnglish
Pages (from-to)5045-5047
Number of pages3
JournalChemical Communications
Issue number48
DOIs
Publication statusPublished - 2006 Dec 11

Fingerprint

Phosphinic Acids
Cinchona Alkaloids
Addition reactions
Oximes
Ammonium Compounds
Ether
Ethers
Salts
Acids
glyoxylic acid

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

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title = "Enantioselective radical addition reactions to the C=N bond utilizing chiral quaternary ammonium salts of hypophosphorous acid in aqueous media",
abstract = "An enantioselective addition of alkyl radicals to glyoxylate oxime ether mediated by Cinchona alkaloid derived chiral ammonium salts of hypophosphorous acid, QP and QDP, has been developed.",
author = "Cho, {Dae Hyan} and Jang, {Doo Ok}",
year = "2006",
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day = "11",
doi = "10.1039/b613045c",
language = "English",
pages = "5045--5047",
journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
number = "48",

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