Enhanced moisture barrier films based on EVOH/exfoliated graphite (EGn) nanocomposite films by solution blending

Hyok Kwon, Dowan Kim, Jongchul Seo, Haksoo Han

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

A series of ethyl-vinyl alcohol (EVOH) nanocomposite films with exfoliated graphite nanosheets (EGn) were prepared via a solution blending method and their physical and moisture barrier properties were investigated as a function of the EGn content. The physical properties were strongly dependent upon the chemical and morphological structures originating from the differences in EGn composition. The nanocomposite films showed no strong interactions between the polymer and EGn filler, and this resulted in poor dispersion in relatively high content EVOH/EGn nanocomposites. With increasing content of EGn particles, the water vapor transmission rate varied in the range of 1.29 to 3.14 cc/m 2/day and the water uptake greatly decreased from 9.1 to 3.4 wt%. The water resistance capacity of EVOH was greatly enhanced and moisture diffusion in the pure EVOH film was retarded by introducing the EGn. However, thermal stabilities were not improved by incorporating EGn due to the poor interaction between EVOH polymer chains and the EGn surface. [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)987-994
Number of pages8
JournalMacromolecular Research
Volume21
Issue number9
DOIs
Publication statusPublished - 2013 Sep 1

Fingerprint

Nanocomposite films
Graphite
Nanosheets
Alcohols
Moisture
Polymers
Water
Steam
Water vapor
Fillers
Nanocomposites
Thermodynamic stability
Physical properties

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

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title = "Enhanced moisture barrier films based on EVOH/exfoliated graphite (EGn) nanocomposite films by solution blending",
abstract = "A series of ethyl-vinyl alcohol (EVOH) nanocomposite films with exfoliated graphite nanosheets (EGn) were prepared via a solution blending method and their physical and moisture barrier properties were investigated as a function of the EGn content. The physical properties were strongly dependent upon the chemical and morphological structures originating from the differences in EGn composition. The nanocomposite films showed no strong interactions between the polymer and EGn filler, and this resulted in poor dispersion in relatively high content EVOH/EGn nanocomposites. With increasing content of EGn particles, the water vapor transmission rate varied in the range of 1.29 to 3.14 cc/m 2/day and the water uptake greatly decreased from 9.1 to 3.4 wt{\%}. The water resistance capacity of EVOH was greatly enhanced and moisture diffusion in the pure EVOH film was retarded by introducing the EGn. However, thermal stabilities were not improved by incorporating EGn due to the poor interaction between EVOH polymer chains and the EGn surface. [Figure not available: see fulltext.]",
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Enhanced moisture barrier films based on EVOH/exfoliated graphite (EGn) nanocomposite films by solution blending. / Kwon, Hyok; Kim, Dowan; Seo, Jongchul; Han, Haksoo.

In: Macromolecular Research, Vol. 21, No. 9, 01.09.2013, p. 987-994.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Enhanced moisture barrier films based on EVOH/exfoliated graphite (EGn) nanocomposite films by solution blending

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AB - A series of ethyl-vinyl alcohol (EVOH) nanocomposite films with exfoliated graphite nanosheets (EGn) were prepared via a solution blending method and their physical and moisture barrier properties were investigated as a function of the EGn content. The physical properties were strongly dependent upon the chemical and morphological structures originating from the differences in EGn composition. The nanocomposite films showed no strong interactions between the polymer and EGn filler, and this resulted in poor dispersion in relatively high content EVOH/EGn nanocomposites. With increasing content of EGn particles, the water vapor transmission rate varied in the range of 1.29 to 3.14 cc/m 2/day and the water uptake greatly decreased from 9.1 to 3.4 wt%. The water resistance capacity of EVOH was greatly enhanced and moisture diffusion in the pure EVOH film was retarded by introducing the EGn. However, thermal stabilities were not improved by incorporating EGn due to the poor interaction between EVOH polymer chains and the EGn surface. [Figure not available: see fulltext.]

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