Enhanced oxygen-barrier and water-resistance properties of poly(vinyl alcohol) blended with poly(acrylic acid) for packaging applications

Mijin Lim, Dowan Kim, Jongchul Seo

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

To enhance the oxygen-barrier and water-resistance properties of poly(vinyl alcohol) (PVA) and expand its food packaging applicability, five crosslinked poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) blend films were prepared via esterification reactions between hydroxyl groups in PVA and carboxylic acid groups in PAA. The physical characteristics of the blends, including the thermal, barrier, mechanical and optical properties, were investigated as a function of PAA ratio. With increasing PAA content, the crosslinking density was significantly increased, resulting in changes in the chemical structure, morphology and crystallinity of the films. The oxygen transmission rate of pure PVA decreased from 5.91 to 1.59 cc m-1 day-1 with increasing PAA ratio. The water resistance, too, increased remarkably. All the blend films showed good optical transparency. The physical properties of the blend films were strongly correlated with the chemical structure and morphology changes, which varied with the PAA content.

Original languageEnglish
Pages (from-to)400-406
Number of pages7
JournalPolymer International
Volume65
Issue number4
DOIs
Publication statusPublished - 2016 Apr 1

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carbopol 940
Acrylics
Packaging
Alcohols
Oxygen
Acids
Water
Esterification
Carboxylic Acids
Carboxylic acids
Hydroxyl Radical
Crosslinking
Transparency
Optical properties
Physical properties
Mechanical properties

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

Cite this

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Enhanced oxygen-barrier and water-resistance properties of poly(vinyl alcohol) blended with poly(acrylic acid) for packaging applications. / Lim, Mijin; Kim, Dowan; Seo, Jongchul.

In: Polymer International, Vol. 65, No. 4, 01.04.2016, p. 400-406.

Research output: Contribution to journalArticle

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