Enhanced Performance of Mixed-Matrix Membranes through a Graft Copolymer-Directed Interface and Interaction Tuning Approach

Won Seok Chi, Sang Jin Kim, Seung Joon Lee, Youn-Sang Bae, Jong Hak Kim

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Herein, a high performance mixed-matrix membrane (MMM) is reported with simultaneously large improvements in the CO2 permeability by 880% from 70.2 to 687.7 Barrer (1 Barrer=1×10-10 cm3 cm cm-2 s-1 cmHg-1) and CO2/N2 selectivity by 14.4% from 30.5 to 34.9. These findings represent one of the most dramatic improvements ever reported for MMMs. These improvements are obtained through an interface and interaction tuning approach based on an amphiphilic grafted copolymer. Poly(vinyl chloride)-g-poly(oxyethylene methacrylate) (PVC-g-POEM) graft copolymer plays a key role as a soft organic matrix to provide good permeation properties, uniform distribution of zeolite imidazole frameworks-8 (ZIF-8), and better interfacial contact with inorganic compounds. In particular, the CO2/C3H8 and CO2/C3H6 selectivities reached 10.5 and 42.7, respectively, for PVC-g-POEM/ZIF (40 %) MMMs; this indicates that it could be a promising membrane material for the purification of C3 hydrocarbons.

Original languageEnglish
Pages (from-to)650-658
Number of pages9
JournalChemSusChem
Volume8
Issue number4
DOIs
Publication statusPublished - 2015 Feb 1

Fingerprint

Graft copolymers
Tuning
chloride
membrane
Membranes
Zeolites
Inorganic compounds
inorganic compound
matrix
Hydrocarbons
Permeation
zeolite
Purification
purification
Copolymers
permeability
hydrocarbon
poly(vinyl chloride)-g-poly(oxyethylene methacrylate)
imidazole
material

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)

Cite this

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abstract = "Herein, a high performance mixed-matrix membrane (MMM) is reported with simultaneously large improvements in the CO2 permeability by 880{\%} from 70.2 to 687.7 Barrer (1 Barrer=1×10-10 cm3 cm cm-2 s-1 cmHg-1) and CO2/N2 selectivity by 14.4{\%} from 30.5 to 34.9. These findings represent one of the most dramatic improvements ever reported for MMMs. These improvements are obtained through an interface and interaction tuning approach based on an amphiphilic grafted copolymer. Poly(vinyl chloride)-g-poly(oxyethylene methacrylate) (PVC-g-POEM) graft copolymer plays a key role as a soft organic matrix to provide good permeation properties, uniform distribution of zeolite imidazole frameworks-8 (ZIF-8), and better interfacial contact with inorganic compounds. In particular, the CO2/C3H8 and CO2/C3H6 selectivities reached 10.5 and 42.7, respectively, for PVC-g-POEM/ZIF (40 {\%}) MMMs; this indicates that it could be a promising membrane material for the purification of C3 hydrocarbons.",
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Enhanced Performance of Mixed-Matrix Membranes through a Graft Copolymer-Directed Interface and Interaction Tuning Approach. / Chi, Won Seok; Kim, Sang Jin; Lee, Seung Joon; Bae, Youn-Sang; Kim, Jong Hak.

In: ChemSusChem, Vol. 8, No. 4, 01.02.2015, p. 650-658.

Research output: Contribution to journalArticle

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