Enhanced Photoinduced Carrier Generation Efficiency through Surface Band Bending in Topological Insulator Bi2Se3Thin Films by the Oxidized Layer

Seok Bo Hong, Seok Bo Hong, Dae Kyoung Kim, Dae Kyoung Kim, Jimin Chae, Jimin Chae, Kiwoong Kim, Kwangsik Jeong, Kwangsik Jeong, Jonghoon Kim, Jonghoon Kim, Hanbum Park, Hanbum Park, Yeonjin Yi, Mann Ho Cho, Mann Ho Cho

Research output: Contribution to journalArticle

Abstract

Topological insulators (TIs) have become popular in the field of optoelectronic devices because of their broadband and high-sensitivity properties, which are attributed to the narrow band gap of the bulk state and high mobility of the Dirac surface state. Although perfectly grown TIs are known to exhibit strong stability against oxidation, in most cases, the existence of vacancy defects in TIs reacts to air and the characteristics of TIs is affected by oxidation. Therefore, changes in the band structure and electrical characteristics by oxidation should be considered. A significant change occurs because of the oxidation; however, the dependence of the photoresponse of TIs on oxidation has not been studied in detail. In this study, the photoresponsivity of oxidized Bi2Se3 films is enhanced, rather than degraded, after oxidation in air for 24 h, resulting in a maximum responsivity of 140 mA W-1. This responsivity is substantially higher than previously reported values for Bi2Se3. Furthermore, a change in the photoresponse time of Bi2Se3 due to air exposure is systematically observed. Based on variations in the Fermi level and work function, using photoelectron spectroscopy, it is confirmed that the responsivity is improved from the junction effect of the Bi-based surface oxidized layer.

Original languageEnglish
Pages (from-to)26649-26658
Number of pages10
JournalACS Applied Materials and Interfaces
Volume12
Issue number23
DOIs
Publication statusPublished - 2020 Jun 10

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

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    Hong, S. B., Hong, S. B., Kim, D. K., Kim, D. K., Chae, J., Chae, J., Kim, K., Jeong, K., Jeong, K., Kim, J., Kim, J., Park, H., Park, H., Yi, Y., Cho, M. H., & Cho, M. H. (2020). Enhanced Photoinduced Carrier Generation Efficiency through Surface Band Bending in Topological Insulator Bi2Se3Thin Films by the Oxidized Layer. ACS Applied Materials and Interfaces, 12(23), 26649-26658. https://doi.org/10.1021/acsami.0c05165