Enhancement of conductivity and transparency for of poly(3,4-ethylenedioxythiophene) films using photo-acid generator as dopant

Se Jin Kwon; Woong Cheol Seok; Jong Tae Leem; Ju Hui Kang; Won Gun Koh; Ho Jun Song; Sangkug Lee

doi:10.1016/j.polymer.2018.05.067

Enhancement of conductivity and transparency for of poly(3,4-ethylenedioxythiophene) films using photo-acid generator as dopant

Se Jin Kwon, Woong Cheol Seok, Jong Tae Leem, Ju Hui Kang, Won Gun Koh, Ho Jun Song, Sangkug Lee

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We introduced the photoacid generator as dopant of photon energy to improve the conductivity of PEDOT:PSS films and form patterned film. The PEDOT:PSS film using PAG-001 exhibited the lowest sheet resistance of 156 Ω/sq at the photon energy of 1 J (10 wt% of PAG-001 in IPA). Also, the PEDOT:PSS film using PAG-301s exhibited the lowest sheet resistance of 154 Ω/sq at the photon energy of 1 J (10 wt% of PAG-301s in IPA). In terms of durability, the sheet resistance of the PEDOT:PSS film with PAG increased to 10% after 10 days, which shows better stability than that of PEDOT:PSS film with DMSO (10% 3 days). We introduced piperidine to increase sheet resistance gaps between conductive and insulating region. In the case of piperidine treatment, the sheet resistance of the conductive region showed 243 Ω/sq, and that of the insulating region showed 2.6*10⁷ Ω/sq. In one film, the difference of sheet resistance between the conductive and insulating regions increased from 10³ to 10⁵ times.

Original language	English
Pages (from-to)	30-37
Number of pages	8
Journal	polymer
Volume	147
DOIs	https://doi.org/10.1016/j.polymer.2018.05.067
Publication status	Published - 2018 Jul 4

Bibliographical note

Funding Information:
This work was supported by the Industrial Strategic Technology Development Program ( #10053627 ) funded by the Ministry of Trade, Industry and Energy, Korea . We acknowledge financial support for this research by the Internal Research Program of Korea Institute of Industrial Technology ( PEO 18032 ).

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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@article{26383a689082428d90be4b30ea5ef3d0,

title = "Enhancement of conductivity and transparency for of poly(3,4-ethylenedioxythiophene) films using photo-acid generator as dopant",

abstract = "We introduced the photoacid generator as dopant of photon energy to improve the conductivity of PEDOT:PSS films and form patterned film. The PEDOT:PSS film using PAG-001 exhibited the lowest sheet resistance of 156 Ω/sq at the photon energy of 1 J (10 wt% of PAG-001 in IPA). Also, the PEDOT:PSS film using PAG-301s exhibited the lowest sheet resistance of 154 Ω/sq at the photon energy of 1 J (10 wt% of PAG-301s in IPA). In terms of durability, the sheet resistance of the PEDOT:PSS film with PAG increased to 10% after 10 days, which shows better stability than that of PEDOT:PSS film with DMSO (10% 3 days). We introduced piperidine to increase sheet resistance gaps between conductive and insulating region. In the case of piperidine treatment, the sheet resistance of the conductive region showed 243 Ω/sq, and that of the insulating region showed 2.6*107 Ω/sq. In one film, the difference of sheet resistance between the conductive and insulating regions increased from 103 to 105 times.",

author = "Kwon, {Se Jin} and Seok, {Woong Cheol} and Leem, {Jong Tae} and Kang, {Ju Hui} and Koh, {Won Gun} and Song, {Ho Jun} and Sangkug Lee",

note = "Funding Information: This work was supported by the Industrial Strategic Technology Development Program ( #10053627 ) funded by the Ministry of Trade, Industry and Energy, Korea . We acknowledge financial support for this research by the Internal Research Program of Korea Institute of Industrial Technology ( PEO 18032 ). ",

year = "2018",

month = jul,

day = "4",

doi = "10.1016/j.polymer.2018.05.067",

language = "English",

volume = "147",

pages = "30--37",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Enhancement of conductivity and transparency for of poly(3,4-ethylenedioxythiophene) films using photo-acid generator as dopant

AU - Kwon, Se Jin

AU - Seok, Woong Cheol

AU - Leem, Jong Tae

AU - Kang, Ju Hui

AU - Koh, Won Gun

AU - Song, Ho Jun

AU - Lee, Sangkug

N1 - Funding Information: This work was supported by the Industrial Strategic Technology Development Program ( #10053627 ) funded by the Ministry of Trade, Industry and Energy, Korea . We acknowledge financial support for this research by the Internal Research Program of Korea Institute of Industrial Technology ( PEO 18032 ).

PY - 2018/7/4

Y1 - 2018/7/4

N2 - We introduced the photoacid generator as dopant of photon energy to improve the conductivity of PEDOT:PSS films and form patterned film. The PEDOT:PSS film using PAG-001 exhibited the lowest sheet resistance of 156 Ω/sq at the photon energy of 1 J (10 wt% of PAG-001 in IPA). Also, the PEDOT:PSS film using PAG-301s exhibited the lowest sheet resistance of 154 Ω/sq at the photon energy of 1 J (10 wt% of PAG-301s in IPA). In terms of durability, the sheet resistance of the PEDOT:PSS film with PAG increased to 10% after 10 days, which shows better stability than that of PEDOT:PSS film with DMSO (10% 3 days). We introduced piperidine to increase sheet resistance gaps between conductive and insulating region. In the case of piperidine treatment, the sheet resistance of the conductive region showed 243 Ω/sq, and that of the insulating region showed 2.6*107 Ω/sq. In one film, the difference of sheet resistance between the conductive and insulating regions increased from 103 to 105 times.

AB - We introduced the photoacid generator as dopant of photon energy to improve the conductivity of PEDOT:PSS films and form patterned film. The PEDOT:PSS film using PAG-001 exhibited the lowest sheet resistance of 156 Ω/sq at the photon energy of 1 J (10 wt% of PAG-001 in IPA). Also, the PEDOT:PSS film using PAG-301s exhibited the lowest sheet resistance of 154 Ω/sq at the photon energy of 1 J (10 wt% of PAG-301s in IPA). In terms of durability, the sheet resistance of the PEDOT:PSS film with PAG increased to 10% after 10 days, which shows better stability than that of PEDOT:PSS film with DMSO (10% 3 days). We introduced piperidine to increase sheet resistance gaps between conductive and insulating region. In the case of piperidine treatment, the sheet resistance of the conductive region showed 243 Ω/sq, and that of the insulating region showed 2.6*107 Ω/sq. In one film, the difference of sheet resistance between the conductive and insulating regions increased from 103 to 105 times.

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