Enhancing the catalytic performance of cobalt oxide by doping on ceria in the high temperature water-gas shift reaction

Ajay Jha, Dae Woon Jeong, Yeol Lim Lee, In Wook Nah, Hyun Seog Roh

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The high temperature water-gas shift (HT-WGS) reaction was performed using a Co-CeO2 catalyst, prepared through a co-precipitation method. The catalyst showed stable activity performance at 400°C with 90% CO conversion without any side reactions (methanation) at a very high GHSV of 143 000 h-1, which is the highest value reported for the HT-WGS reaction. This remarkable performance is attributed to the superior reducible nature of ceria and the preferential exposure of (220) and (112) facets of CeO2 and Co3O4, respectively. The time-on-stream study substantiates that ceria stabilizes the surface area of the Co-CeO2 catalyst during the WGS reaction compared to the bulk Co3O4.

Original languageEnglish
Pages (from-to)103023-103029
Number of pages7
JournalRSC Advances
Volume5
Issue number125
DOIs
Publication statusPublished - 2015 Nov 27

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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