Enhancing the Performance of Inverted Organic Photovoltaics Using Cathode Interlayers Based on Solution-Processable Tetrabutylammonium Halides

Gyeongho Hyun, Dongguen Shin, Hyunbok Lee, Yeonjin Yi

Research output: Contribution to journalLetter

1 Citation (Scopus)

Abstract

High-performance inverted organic photovoltaics (OPVs) require the work function of transparent bottom cathodes to be low, which can be efficiently achieved by inserting an ultrathin interlayer to form an interface dipole. Herein, solution-processable tetrabutylammonium halides (TBAXs, X = Cl, Br, and I) are employed as a cathode interlayer in inverted OPVs, leading to the disappearance of an S-shaped kink in their current density–voltage curves and increasing their open-circuit voltages and fill factors, which resulted in significantly enhanced power conversion efficiencies. Ultraviolet photoelectron spectroscopy measurements revealed that the work function of indium tin oxide (ITO) was considerably lowered in the presence of TBAX interlayers, resulting in efficient electron extraction from the C60 acceptor to the ITO bottom cathode and increasing the built-in potential across devices. Thus, TBAXs are demonstrated to be promising materials for efficient cathode interlayer formation in inverted OPVs.

Original languageEnglish
Article number1700250
JournalPhysica Status Solidi - Rapid Research Letters
Volume11
Issue number10
DOIs
Publication statusPublished - 2017 Oct 1

Fingerprint

halides
interlayers
Cathodes
cathodes
Tin oxides
indium oxides
Indium
tin oxides
Ultraviolet photoelectron spectroscopy
ultraviolet spectroscopy
Open circuit voltage
open circuit voltage
Conversion efficiency
photoelectron spectroscopy
dipoles
tetrabutylammonium
Electrons
curves
electrons
indium tin oxide

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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abstract = "High-performance inverted organic photovoltaics (OPVs) require the work function of transparent bottom cathodes to be low, which can be efficiently achieved by inserting an ultrathin interlayer to form an interface dipole. Herein, solution-processable tetrabutylammonium halides (TBAXs, X = Cl, Br, and I) are employed as a cathode interlayer in inverted OPVs, leading to the disappearance of an S-shaped kink in their current density–voltage curves and increasing their open-circuit voltages and fill factors, which resulted in significantly enhanced power conversion efficiencies. Ultraviolet photoelectron spectroscopy measurements revealed that the work function of indium tin oxide (ITO) was considerably lowered in the presence of TBAX interlayers, resulting in efficient electron extraction from the C60 acceptor to the ITO bottom cathode and increasing the built-in potential across devices. Thus, TBAXs are demonstrated to be promising materials for efficient cathode interlayer formation in inverted OPVs.",
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Enhancing the Performance of Inverted Organic Photovoltaics Using Cathode Interlayers Based on Solution-Processable Tetrabutylammonium Halides. / Hyun, Gyeongho; Shin, Dongguen; Lee, Hyunbok; Yi, Yeonjin.

In: Physica Status Solidi - Rapid Research Letters, Vol. 11, No. 10, 1700250, 01.10.2017.

Research output: Contribution to journalLetter

TY - JOUR

T1 - Enhancing the Performance of Inverted Organic Photovoltaics Using Cathode Interlayers Based on Solution-Processable Tetrabutylammonium Halides

AU - Hyun, Gyeongho

AU - Shin, Dongguen

AU - Lee, Hyunbok

AU - Yi, Yeonjin

PY - 2017/10/1

Y1 - 2017/10/1

N2 - High-performance inverted organic photovoltaics (OPVs) require the work function of transparent bottom cathodes to be low, which can be efficiently achieved by inserting an ultrathin interlayer to form an interface dipole. Herein, solution-processable tetrabutylammonium halides (TBAXs, X = Cl, Br, and I) are employed as a cathode interlayer in inverted OPVs, leading to the disappearance of an S-shaped kink in their current density–voltage curves and increasing their open-circuit voltages and fill factors, which resulted in significantly enhanced power conversion efficiencies. Ultraviolet photoelectron spectroscopy measurements revealed that the work function of indium tin oxide (ITO) was considerably lowered in the presence of TBAX interlayers, resulting in efficient electron extraction from the C60 acceptor to the ITO bottom cathode and increasing the built-in potential across devices. Thus, TBAXs are demonstrated to be promising materials for efficient cathode interlayer formation in inverted OPVs.

AB - High-performance inverted organic photovoltaics (OPVs) require the work function of transparent bottom cathodes to be low, which can be efficiently achieved by inserting an ultrathin interlayer to form an interface dipole. Herein, solution-processable tetrabutylammonium halides (TBAXs, X = Cl, Br, and I) are employed as a cathode interlayer in inverted OPVs, leading to the disappearance of an S-shaped kink in their current density–voltage curves and increasing their open-circuit voltages and fill factors, which resulted in significantly enhanced power conversion efficiencies. Ultraviolet photoelectron spectroscopy measurements revealed that the work function of indium tin oxide (ITO) was considerably lowered in the presence of TBAX interlayers, resulting in efficient electron extraction from the C60 acceptor to the ITO bottom cathode and increasing the built-in potential across devices. Thus, TBAXs are demonstrated to be promising materials for efficient cathode interlayer formation in inverted OPVs.

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