Stabilization of the SEI layer that is formed by consuming active lithium in electrolytes is a critical issue for improving the cyclability of lithium ion batteries. We used SiNSs as anodes and investigated the effect of fluoroethylene carbonate (FEC) additives on the SEI layer. Our XPS, EIS and TEM analysis of C[sbnd]O and C[dbnd]O bonds, interfacial resistance and thickness of SEl layer, respectively, shows that the FEC produces electrochemically and mechanically stable SEI layer. The SiNSs with FEC showed the capacity of over 1500 mA h g−1 with 95% efficiency after 200 cycles.
Bibliographical noteFunding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (No. 2017R1A2B3011586), Nano, Material Technology Development Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology, South Korea (2014M3A7B4051594) and the National Research Foundation of Korea Grant funded by the Korean Government (MSIP) (NRF-2011-C1AAA001-0030538).
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry