Exfoliation of Layered Topological Insulators Bi2Se3 and Bi2Te3 via Electrochemistry

Adriano Ambrosi, Zdeněk Sofer, Jan Luxa, Martin Pumera

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40 Citations (Scopus)

Abstract

Among layered materials, topological insulators such as Bi2Se3 and Bi2Te3 are lately attracting much attention due to particular electronic properties and, especially with Bi2Te3, excellent thermoelectric properties. Methods of preparation of few-layered nanosheets of Bi2Se3 and Bi2Te3 range from the bottom-up chemical vapor deposition or hydrothermal synthesis from oxide precursors to the top-down mechanical exfoliation and liquid-based exfoliation supported by sonication from the natural bulk crystals. Here, we propose a simple and rapid electrochemical approach to exfoliate natural Bi2Se3 and Bi2Te3 crystals in aqueous media to single/few-layer sheets. The exfoliated materials have been characterized by scanning transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray powder diffraction, high-resolution transmission electron microscopy, and Raman spectroscopy in addition to evaluation of their electrochemical properties. This electrochemical procedure represents a simple, reagent-free, and scalable method for the fabrication of single/few-layer sheets of these materials.

Original languageEnglish
Pages (from-to)11442-11448
Number of pages7
JournalACS Nano
Volume10
Issue number12
DOIs
Publication statusPublished - 2016 Dec 27

Bibliographical note

Funding Information:
M.P. acknowledges a Tier 2 grant (MOE2013-T2-1-056; ARC 35/13) from the Ministry of Education, Singapore. Z.S. and J.L. were supported by Czech Science Foundation (GACR No. 16- 05167S) and by specific university research (MSMT No. 20- SVV/2016).

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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