Extraction-based recovery of RDX from obsolete Composition B

Hyewon Kang; Hyejoo Kim; Chang Ha Lee; Ik Sung Ahn; Keun Deuk Lee

doi:10.1016/j.jiec.2017.07.036

Extraction-based recovery of RDX from obsolete Composition B

Hyewon Kang, Hyejoo Kim, Chang Ha Lee, Ik Sung Ahn, Keun Deuk Lee

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Recovery of explosives from obsolete ammunition has been considered an eco-friendly alternative to conventional dumping or detonation disposal methods Composition B, made of 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and paraffin wax, has been used as the main explosive filling in various munitions. It was selected as a model explosive for this study. TNT was extracted from Composition B by exploiting the different solubilities of TNT and RDX in acetonitrile. After removing paraffin wax by hexane washing, RDX was recovered from unused Composition B with a purity higher than 99% and a yield of 84%.

Original language	English
Pages (from-to)	394-398
Number of pages	5
Journal	Journal of Industrial and Engineering Chemistry
Volume	56
DOIs	https://doi.org/10.1016/j.jiec.2017.07.036
Publication status	Published - 2017 Dec 25

All Science Journal Classification (ASJC) codes

Chemical Engineering(all)

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title = "Extraction-based recovery of RDX from obsolete Composition B",

abstract = "Recovery of explosives from obsolete ammunition has been considered an eco-friendly alternative to conventional dumping or detonation disposal methods Composition B, made of 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and paraffin wax, has been used as the main explosive filling in various munitions. It was selected as a model explosive for this study. TNT was extracted from Composition B by exploiting the different solubilities of TNT and RDX in acetonitrile. After removing paraffin wax by hexane washing, RDX was recovered from unused Composition B with a purity higher than 99% and a yield of 84%.",

author = "Hyewon Kang and Hyejoo Kim and Lee, {Chang Ha} and Ahn, {Ik Sung} and Lee, {Keun Deuk}",

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T1 - Extraction-based recovery of RDX from obsolete Composition B

AU - Kang, Hyewon

AU - Kim, Hyejoo

AU - Lee, Chang Ha

AU - Ahn, Ik Sung

AU - Lee, Keun Deuk

PY - 2017/12/25

Y1 - 2017/12/25

N2 - Recovery of explosives from obsolete ammunition has been considered an eco-friendly alternative to conventional dumping or detonation disposal methods Composition B, made of 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and paraffin wax, has been used as the main explosive filling in various munitions. It was selected as a model explosive for this study. TNT was extracted from Composition B by exploiting the different solubilities of TNT and RDX in acetonitrile. After removing paraffin wax by hexane washing, RDX was recovered from unused Composition B with a purity higher than 99% and a yield of 84%.

AB - Recovery of explosives from obsolete ammunition has been considered an eco-friendly alternative to conventional dumping or detonation disposal methods Composition B, made of 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and paraffin wax, has been used as the main explosive filling in various munitions. It was selected as a model explosive for this study. TNT was extracted from Composition B by exploiting the different solubilities of TNT and RDX in acetonitrile. After removing paraffin wax by hexane washing, RDX was recovered from unused Composition B with a purity higher than 99% and a yield of 84%.

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