In this study, we successfully design and synthesize the mesoporous carbon coated carbon nanofibers (CNF@mesoCs) for the Li-air battery. The composites are fabricated via electrospinning technique and nanocasting strategy. After mesoporous carbon coating process, the composites have retained their original one-dimensional structure as pristine carbon nanofibers. Every nanofiber entangles with each other to form a three-dimensional cross-linked web structure. Because of the mesoporous carbon coating on carbon nanofibers, the surface area increases from 708 m 2 g -1 to 2194 m 2 g -1 . We confirm that the mesoporous carbon coated on carbon nanofibers is well-graphitized by analysis of Raman spectra. The graphitized surface of CNF@mesoCs (4.638 S cm -1 ) is believed to result in their higher electrical conductivity than that of pristine carbon nanofibers (3.0759 S cm -1 ). Without employment of any binders and metal foams, the cathode of CNF@mesoCs exhibits high discharge capacity of 4000 mA h g -1 , which is much higher than that from pristine carbon nanofibers (2750 mA h g -1 ). This work demonstrates that the fabricated CNF@mesoCs structures have a great potential to be employed as light-weight and efficient electrode for energy storage and conversion devices.
Bibliographical noteFunding Information:
This research was supported by the MSIP (Ministry of Science, ICT and Future Planning), Korea, under the “IT Consilience Creative Program” (NIPA-2014-H0201-14-1002) supervised by the NIPA (National IT Industry Promotion Agency).
© 2014 Elsevier B.V. All rights reserved.
All Science Journal Classification (ASJC) codes
- Condensed Matter Physics
- Physics and Astronomy(all)
- Surfaces and Interfaces
- Surfaces, Coatings and Films