Fabrication of transparent conductive carbon nanotubes/polyurethane-urea composite films by solvent evaporation-induced self-assembly (EISA)

Ho Seung Ki; Jeong Hyun Yeum; Soonja Choe; Jung Hyun Kim; In Woo Cheong

doi:10.1016/j.compscitech.2008.12.012

Fabrication of transparent conductive carbon nanotubes/polyurethane-urea composite films by solvent evaporation-induced self-assembly (EISA)

Ho Seung Ki, Jeong Hyun Yeum, Soonja Choe, Jung Hyun Kim, In Woo Cheong

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Transparent and conductive carbon nanotubes (CNTs)/polyurethane-urea (PUU) composite films were prepared by solvent evaporation-induced self-assembly (EISA). Pristine CNTs were treated with acids (H₂SO₄/HNO₃ = 3:1, v:v), acylated with thionyl chloride, and purified after filtration. These acylated CNTs (0.05 wt.% in dimethylformamide, DMF) were deposited onto the 3-aminopropyl triethoxysilane (APTES)-modified glass substrate by DMF EISA at 100 °C with the withdrawal rate of 3 cm/h. The CNT layers of 200-400 nm thicknesses were transferred to the PUU films by solution casting or resin transfer molding (RTM) at ambient temperature. Optical transmittances of the composite films were 60-75% at 550 nm wavelength and their sheet resistances were 5.2 × 10⁰-2.4 × 10³ kΩ/square, and which varied significantly with type of CNTs and the transferring methods of CNT layers.

Original language	English
Pages (from-to)	645-650
Number of pages	6
Journal	Composites Science and Technology
Volume	69
Issue number	5
DOIs	https://doi.org/10.1016/j.compscitech.2008.12.012
Publication status	Published - 2009 Apr

Bibliographical note

Funding Information:
This research was supported by Kyungpook National University Research Fund, 2007.

All Science Journal Classification (ASJC) codes

Ceramics and Composites
Engineering(all)

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10.1016/j.compscitech.2008.12.012

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title = "Fabrication of transparent conductive carbon nanotubes/polyurethane-urea composite films by solvent evaporation-induced self-assembly (EISA)",

abstract = "Transparent and conductive carbon nanotubes (CNTs)/polyurethane-urea (PUU) composite films were prepared by solvent evaporation-induced self-assembly (EISA). Pristine CNTs were treated with acids (H2SO4/HNO3 = 3:1, v:v), acylated with thionyl chloride, and purified after filtration. These acylated CNTs (0.05 wt.% in dimethylformamide, DMF) were deposited onto the 3-aminopropyl triethoxysilane (APTES)-modified glass substrate by DMF EISA at 100 °C with the withdrawal rate of 3 cm/h. The CNT layers of 200-400 nm thicknesses were transferred to the PUU films by solution casting or resin transfer molding (RTM) at ambient temperature. Optical transmittances of the composite films were 60-75% at 550 nm wavelength and their sheet resistances were 5.2 × 100-2.4 × 103 kΩ/square, and which varied significantly with type of CNTs and the transferring methods of CNT layers.",

author = "Ki, {Ho Seung} and Yeum, {Jeong Hyun} and Soonja Choe and Kim, {Jung Hyun} and Cheong, {In Woo}",

note = "Funding Information: This research was supported by Kyungpook National University Research Fund, 2007.",

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doi = "10.1016/j.compscitech.2008.12.012",

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volume = "69",

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AU - Ki, Ho Seung

AU - Yeum, Jeong Hyun

AU - Choe, Soonja

AU - Kim, Jung Hyun

AU - Cheong, In Woo

N1 - Funding Information: This research was supported by Kyungpook National University Research Fund, 2007.

PY - 2009/4

Y1 - 2009/4

N2 - Transparent and conductive carbon nanotubes (CNTs)/polyurethane-urea (PUU) composite films were prepared by solvent evaporation-induced self-assembly (EISA). Pristine CNTs were treated with acids (H2SO4/HNO3 = 3:1, v:v), acylated with thionyl chloride, and purified after filtration. These acylated CNTs (0.05 wt.% in dimethylformamide, DMF) were deposited onto the 3-aminopropyl triethoxysilane (APTES)-modified glass substrate by DMF EISA at 100 °C with the withdrawal rate of 3 cm/h. The CNT layers of 200-400 nm thicknesses were transferred to the PUU films by solution casting or resin transfer molding (RTM) at ambient temperature. Optical transmittances of the composite films were 60-75% at 550 nm wavelength and their sheet resistances were 5.2 × 100-2.4 × 103 kΩ/square, and which varied significantly with type of CNTs and the transferring methods of CNT layers.

AB - Transparent and conductive carbon nanotubes (CNTs)/polyurethane-urea (PUU) composite films were prepared by solvent evaporation-induced self-assembly (EISA). Pristine CNTs were treated with acids (H2SO4/HNO3 = 3:1, v:v), acylated with thionyl chloride, and purified after filtration. These acylated CNTs (0.05 wt.% in dimethylformamide, DMF) were deposited onto the 3-aminopropyl triethoxysilane (APTES)-modified glass substrate by DMF EISA at 100 °C with the withdrawal rate of 3 cm/h. The CNT layers of 200-400 nm thicknesses were transferred to the PUU films by solution casting or resin transfer molding (RTM) at ambient temperature. Optical transmittances of the composite films were 60-75% at 550 nm wavelength and their sheet resistances were 5.2 × 100-2.4 × 103 kΩ/square, and which varied significantly with type of CNTs and the transferring methods of CNT layers.

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Fabrication of transparent conductive carbon nanotubes/polyurethane-urea composite films by solvent evaporation-induced self-assembly (EISA)

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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