Facile isomerization of glucose into fructose using anion-exchange resins in organic solvents and application to direct conversion of glucose into furan compounds

Dasom Mun, Nhan Thanh Thien Huynh, Seunghan Shin, Yong Jin Kim, Sangyong Kim, Yong-Gun Shul, Jin Ku Cho

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The facile isomerization of glucose into fructose has been developed using commercially available anion-exchange resins (AERs) in organic solvents. Following extensive screening for the amount and type of AERs, solvents and reaction time, glucose was transformed into fructose in yields of up to 50% using Amberlite A-26 with macroreticular morphology and tertiary amine functionality in a protic solvent (ethanol). AERs could be used five times without a significant loss of activity. This isomerization method could be applied to the direct conversion of glucose into furan compounds by integrating the dehydration of fructose with cation-exchange resins.

Original languageEnglish
Pages (from-to)5495-5506
Number of pages12
JournalResearch on Chemical Intermediates
Volume43
Issue number10
DOIs
Publication statusPublished - 2017 Oct 1

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Anion Exchange Resins
Isomerization
Fructose
Organic solvents
Glucose
Cation Exchange Resins
Dehydration
Amines
Screening
Ethanol
furan

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Mun, Dasom ; Huynh, Nhan Thanh Thien ; Shin, Seunghan ; Kim, Yong Jin ; Kim, Sangyong ; Shul, Yong-Gun ; Cho, Jin Ku. / Facile isomerization of glucose into fructose using anion-exchange resins in organic solvents and application to direct conversion of glucose into furan compounds. In: Research on Chemical Intermediates. 2017 ; Vol. 43, No. 10. pp. 5495-5506.
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Facile isomerization of glucose into fructose using anion-exchange resins in organic solvents and application to direct conversion of glucose into furan compounds. / Mun, Dasom; Huynh, Nhan Thanh Thien; Shin, Seunghan; Kim, Yong Jin; Kim, Sangyong; Shul, Yong-Gun; Cho, Jin Ku.

In: Research on Chemical Intermediates, Vol. 43, No. 10, 01.10.2017, p. 5495-5506.

Research output: Contribution to journalArticle

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