Facile microwave-assisted synthesis of multiphase CuInSe2 nanoparticles and role of secondary cuse phase on photovoltaic device performance

Yeong Hui Seo, Byung Seok Lee, Yejin Jo, Han Gyeol Kim, Youngmin Choi, Sejin Ahn, Kyunghoon Yoon, Kyoohee Woo, Jooho Moon, Beyong Hwan Ryu, Sunho Jeong

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Multiphase CuInSe2 (CISe) nanoparticles including the secondary CuSe phase are synthesized by a polyol-based, microwave-assisted solvothermal method. It is demonstrated that the reaction chemistry involving formation of the CISe phase is adjusted depending on the heretofore unrecognized chemical nature of polyol solvent, allowing for formation of secondary CuSe phase-incorporated multiphase CISe nanoparticles. The critical role of CuSe phase in generating the pore-free, dense CISe absorber layer for a high-performance thin-film photovoltaic device is investigated through the comparative study on CISe absorber layers derived from both multiphase and single-phase CISe nanoparticles.

Original languageEnglish
Pages (from-to)9529-9536
Number of pages8
JournalJournal of Physical Chemistry C
Volume117
Issue number19
DOIs
Publication statusPublished - 2013 May 16

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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