Facile preparation of Cu(I) impregnated MIL-101(Cr) and its use in a mixed matrix membrane for olefin/paraffin separation

Jung Pyo Jung, Min June Kim, Youn Sang Bae, Jong Hak Kim

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Cu(I) impregnated MIL-100(Cr) [denoted Cu@MIL-101(Cr)] is fabricated by a facile method and utilized in mixed matrix membranes (MMMs) for propylene/propane separation. Cu(I) is prepared from a CuCl2 solution via mild reduction process using sodium sulfite as the reducing agent. The filler is incorporated into a polystyrene-b-polybutadiene-b-polystyrene (SBS) block copolymer matrix to form MMMs. As a result, both the permeability and selectivity of propylene/propane are improved after Cu(I) impregnation. The best performance is obtained for SBS/Cu@MIL-101(Cr) MMM, and these values represent 17% and 54% improvements compared to those of SBS/MIL-101(Cr) MMM, respectively. This result is attributed to the π-complexation of the loaded Cu(I) by propylene gas, indicating that Cu@MIL-101(Cr) with internal Cu(I) and a high pore volume acted as an effective filler to aid propylene/propane separation.

Original languageEnglish
Article number46545
JournalJournal of Applied Polymer Science
Volume135
Issue number31
DOIs
Publication statusPublished - 2018 Aug 15

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation (NRF) grant funded by the Ministry of Science, ICT and Future Planning (NRF-2017R1A4A1014569, NRF-2017M1A2A2043448, NRF-2017R1D1A1B06028030). This work was also supported (in part) by the Yonsei University Future-leading Research Initiative of 2016 (RMS2 2016-22-0108).

Publisher Copyright:
© 2018 Wiley Periodicals, Inc.

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

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