Facile synthesis of hydrophobic, thermally stable, and insulative organically modified silica aerogels using co-precursor method

Vinayak G. Parale, Kyu Yeon Lee, Hae Noo Ree Jung, Ha Yoon Nah, Haryeong Choi, Tae Hee Kim, Varsha D. Phadtare, Hyung Ho Park

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

Silica aerogels have low density and high specific surface area, but there are restrictions regarding their durability and commercialization owing to their fragile nature and the strong moisture absorbing behavior of the siloxane network. To overcome these restrictions, this study evaluated hybrid organically modified silica (ORMOSIL) aerogels by employing 3-(trimethoxysilylpropyl) methacrylate (TMSPM) in tetraethyl orthosilicate (TEOS) through a two-step sol-gel co-precursor method. The methacrylate organic groups were incorporated into the silica networks via reactions between the Si-OH moieties in silica aerogels, resulting in ORMOSIL aerogels. The properties of the ORMOSIL aerogels were strongly affected by the amount of TMSPM co-precursor. The highest concentration of TMSPM (30 wt%) resulted in ORMOSIL aerogels with improved characteristics when compared with the pristine TEOS-based silica aerogels, such as hardness (0.15 GPa), Young's modulus (1.26 GPa), low thermal conductivity (0.038 W/m K), high water contact angle (140°), and high thermal stability (350 °C).

Original languageEnglish
Pages (from-to)3966-3972
Number of pages7
JournalCeramics International
Volume44
Issue number4
DOIs
Publication statusPublished - 2018 Mar

Bibliographical note

Funding Information:
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( 2015R1D1A1A02062229 ). This work was supported by the Center for Advanced Meta-Materials (CAMM) funded by the Ministry of Science, ICT, and Future Planning as Global Frontier Project (CAMM-No. NRF-2014M3A6B3063716 ). The author V.G. Parale would like to thank the Brain Korea 21 (BK21) Project for financial support in the form of a postdoctoral fellowship.

Publisher Copyright:
© 2017 Elsevier Ltd and Techna Group S.r.l.

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

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