Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C60 Ion Beams

Vladimir Pukha; Andrey Belmesov; Alexander Glukhov; Igor Khodos; Mahdi Khadem; Dae Eun Kim; Kirill Krainov; Alexander Shakhmin; Platon Karaseov

doi:10.1007/978-3-030-81119-8_41

Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C₆₀ Ion Beams

Vladimir Pukha, Andrey Belmesov, Alexander Glukhov, Igor Khodos, Mahdi Khadem, Dae Eun Kim, Kirill Krainov, Alexander Shakhmin, Platon Karaseov

Department of Mechanical Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

The regularities of superhard carbon nanocomposite (CNCs) growth on a titanium substrate using accelerated C₆₀ ion beam are investigated. Substrate temperature T_s and ion energy E are the main parameters varied during film growth. The formation of CNC coatings with a specific electrical resistance below 1 Ω × m is observed at a substrate temperature T_s above 300 ºC and ion energies from 5 to 8 keV. CNC coatings obtained at T_s in the range of 300–400 ºC consist of graphite crystals with a size of 1–2 nm enclosed in a diamond-like matrix. The sp²/sp³ bond ratio weakly depends on T_s in this temperature range and slightly decreases with ion energy increase (from 0.33 to 0.26 at 5–8 keV). Diamond-like coating grows on a substrate at T_s lower than 300 ºC by 5 and 7 keV ions. At an ion energy of 8 keV and above sputtering of the substrate was found. In all cases a TiC layer is formed at the substrate-coating interface due to the ion-beam mixing. Formation of this interlayer provides good adhesion of the coating to the substrate. The CNC coating on Ti exhibits high corrosion resistance and good protective properties. Thus, composite carbon films could be used as a conductive electrode in various chemical and bio applications.

Original language	English
Title of host publication	International Youth Conference on Electronics, Telecommunications and Information Technologies - Proceedings of the YETI 2021
Editors	Elena Velichko, Viktoria Kapralova, Platon Karaseov, Sergey Zavjalov, Pablo Angueira, Sergey Andreev
Publisher	Springer Science and Business Media Deutschland GmbH
Pages	385-394
Number of pages	10
ISBN (Print)	9783030811181
DOIs	https://doi.org/10.1007/978-3-030-81119-8_41
Publication status	Published - 2022
Event	International Youth Conference on Electronics, Telecommunications, and Information Technologies, YETI 2021 - Saint Petersburg, Russian Federation Duration: 2021 Apr 22 → 2021 Apr 23

Publication series

Name	Springer Proceedings in Physics
Volume	268
ISSN (Print)	0930-8989
ISSN (Electronic)	1867-4941

Conference

Conference	International Youth Conference on Electronics, Telecommunications, and Information Technologies, YETI 2021
Country/Territory	Russian Federation
City	Saint Petersburg
Period	21/4/22 → 21/4/23

Bibliographical note

Funding Information:
Work was partly supported by Russian Foundation for Basic Research grant # 19-58-51016 and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2019K2A9A1A06097636). Authors thank the Center for Collective Use in Chernogolovka for the usage of JEM-2100 electron microscope. The work at IMT RAS was partly performed in accordance with the Ministry of Science and Higher Education State Task № 075-00355-21-00.

Funding Information:
Acknowledgements Work was partly supported by Russian Foundation for Basic Research grant # 19-58-51016 and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2019K2A9A1A06097636). Authors thank the Center for Collective Use in Chernogolovka for the usage of JEM-2100 electron microscope. The work at IMT RAS was partly performed in accordance with the Ministry of Science and Higher Education State Task № 075-00355-21-00.

Publisher Copyright:
© 2022, The Author(s), under exclusive license to Springer Nature Switzerland AG.

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)

Access to Document

10.1007/978-3-030-81119-8_41

Cite this

Pukha, V., Belmesov, A., Glukhov, A., Khodos, I., Khadem, M., Kim, D. E., Krainov, K., Shakhmin, A., & Karaseov, P. (2022). Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C₆₀ Ion Beams. In E. Velichko, V. Kapralova, P. Karaseov, S. Zavjalov, P. Angueira, & S. Andreev (Eds.), International Youth Conference on Electronics, Telecommunications and Information Technologies - Proceedings of the YETI 2021 (pp. 385-394). (Springer Proceedings in Physics; Vol. 268). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-030-81119-8_41

Pukha, Vladimir ; Belmesov, Andrey ; Glukhov, Alexander et al. / Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C₆₀ Ion Beams. International Youth Conference on Electronics, Telecommunications and Information Technologies - Proceedings of the YETI 2021. editor / Elena Velichko ; Viktoria Kapralova ; Platon Karaseov ; Sergey Zavjalov ; Pablo Angueira ; Sergey Andreev. Springer Science and Business Media Deutschland GmbH, 2022. pp. 385-394 (Springer Proceedings in Physics).

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title = "Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C60 Ion Beams",

abstract = "The regularities of superhard carbon nanocomposite (CNCs) growth on a titanium substrate using accelerated C60 ion beam are investigated. Substrate temperature Ts and ion energy E are the main parameters varied during film growth. The formation of CNC coatings with a specific electrical resistance below 1 Ω × m is observed at a substrate temperature Ts above 300 ºC and ion energies from 5 to 8 keV. CNC coatings obtained at Ts in the range of 300–400 ºC consist of graphite crystals with a size of 1–2 nm enclosed in a diamond-like matrix. The sp2/sp3 bond ratio weakly depends on Ts in this temperature range and slightly decreases with ion energy increase (from 0.33 to 0.26 at 5–8 keV). Diamond-like coating grows on a substrate at Ts lower than 300 ºC by 5 and 7 keV ions. At an ion energy of 8 keV and above sputtering of the substrate was found. In all cases a TiC layer is formed at the substrate-coating interface due to the ion-beam mixing. Formation of this interlayer provides good adhesion of the coating to the substrate. The CNC coating on Ti exhibits high corrosion resistance and good protective properties. Thus, composite carbon films could be used as a conductive electrode in various chemical and bio applications.",

author = "Vladimir Pukha and Andrey Belmesov and Alexander Glukhov and Igor Khodos and Mahdi Khadem and Kim, {Dae Eun} and Kirill Krainov and Alexander Shakhmin and Platon Karaseov",

note = "Funding Information: Work was partly supported by Russian Foundation for Basic Research grant # 19-58-51016 and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2019K2A9A1A06097636). Authors thank the Center for Collective Use in Chernogolovka for the usage of JEM-2100 electron microscope. The work at IMT RAS was partly performed in accordance with the Ministry of Science and Higher Education State Task № 075-00355-21-00. Funding Information: Acknowledgements Work was partly supported by Russian Foundation for Basic Research grant # 19-58-51016 and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2019K2A9A1A06097636). Authors thank the Center for Collective Use in Chernogolovka for the usage of JEM-2100 electron microscope. The work at IMT RAS was partly performed in accordance with the Ministry of Science and Higher Education State Task № 075-00355-21-00. Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive license to Springer Nature Switzerland AG.; International Youth Conference on Electronics, Telecommunications, and Information Technologies, YETI 2021 ; Conference date: 22-04-2021 Through 23-04-2021",

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Pukha, V, Belmesov, A, Glukhov, A, Khodos, I, Khadem, M, Kim, DE, Krainov, K, Shakhmin, A & Karaseov, P 2022, Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C₆₀ Ion Beams. in E Velichko, V Kapralova, P Karaseov, S Zavjalov, P Angueira & S Andreev (eds), International Youth Conference on Electronics, Telecommunications and Information Technologies - Proceedings of the YETI 2021. Springer Proceedings in Physics, vol. 268, Springer Science and Business Media Deutschland GmbH, pp. 385-394, International Youth Conference on Electronics, Telecommunications, and Information Technologies, YETI 2021, Saint Petersburg, Russian Federation, 21/4/22. https://doi.org/10.1007/978-3-030-81119-8_41

Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C₆₀ Ion Beams. / Pukha, Vladimir; Belmesov, Andrey; Glukhov, Alexander et al.

International Youth Conference on Electronics, Telecommunications and Information Technologies - Proceedings of the YETI 2021. ed. / Elena Velichko; Viktoria Kapralova; Platon Karaseov; Sergey Zavjalov; Pablo Angueira; Sergey Andreev. Springer Science and Business Media Deutschland GmbH, 2022. p. 385-394 (Springer Proceedings in Physics; Vol. 268).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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AU - Khadem, Mahdi

AU - Kim, Dae Eun

AU - Krainov, Kirill

AU - Shakhmin, Alexander

AU - Karaseov, Platon

N1 - Funding Information: Work was partly supported by Russian Foundation for Basic Research grant # 19-58-51016 and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2019K2A9A1A06097636). Authors thank the Center for Collective Use in Chernogolovka for the usage of JEM-2100 electron microscope. The work at IMT RAS was partly performed in accordance with the Ministry of Science and Higher Education State Task № 075-00355-21-00. Funding Information: Acknowledgements Work was partly supported by Russian Foundation for Basic Research grant # 19-58-51016 and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2019K2A9A1A06097636). Authors thank the Center for Collective Use in Chernogolovka for the usage of JEM-2100 electron microscope. The work at IMT RAS was partly performed in accordance with the Ministry of Science and Higher Education State Task № 075-00355-21-00. Publisher Copyright: © 2022, The Author(s), under exclusive license to Springer Nature Switzerland AG.

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N2 - The regularities of superhard carbon nanocomposite (CNCs) growth on a titanium substrate using accelerated C60 ion beam are investigated. Substrate temperature Ts and ion energy E are the main parameters varied during film growth. The formation of CNC coatings with a specific electrical resistance below 1 Ω × m is observed at a substrate temperature Ts above 300 ºC and ion energies from 5 to 8 keV. CNC coatings obtained at Ts in the range of 300–400 ºC consist of graphite crystals with a size of 1–2 nm enclosed in a diamond-like matrix. The sp2/sp3 bond ratio weakly depends on Ts in this temperature range and slightly decreases with ion energy increase (from 0.33 to 0.26 at 5–8 keV). Diamond-like coating grows on a substrate at Ts lower than 300 ºC by 5 and 7 keV ions. At an ion energy of 8 keV and above sputtering of the substrate was found. In all cases a TiC layer is formed at the substrate-coating interface due to the ion-beam mixing. Formation of this interlayer provides good adhesion of the coating to the substrate. The CNC coating on Ti exhibits high corrosion resistance and good protective properties. Thus, composite carbon films could be used as a conductive electrode in various chemical and bio applications.

AB - The regularities of superhard carbon nanocomposite (CNCs) growth on a titanium substrate using accelerated C60 ion beam are investigated. Substrate temperature Ts and ion energy E are the main parameters varied during film growth. The formation of CNC coatings with a specific electrical resistance below 1 Ω × m is observed at a substrate temperature Ts above 300 ºC and ion energies from 5 to 8 keV. CNC coatings obtained at Ts in the range of 300–400 ºC consist of graphite crystals with a size of 1–2 nm enclosed in a diamond-like matrix. The sp2/sp3 bond ratio weakly depends on Ts in this temperature range and slightly decreases with ion energy increase (from 0.33 to 0.26 at 5–8 keV). Diamond-like coating grows on a substrate at Ts lower than 300 ºC by 5 and 7 keV ions. At an ion energy of 8 keV and above sputtering of the substrate was found. In all cases a TiC layer is formed at the substrate-coating interface due to the ion-beam mixing. Formation of this interlayer provides good adhesion of the coating to the substrate. The CNC coating on Ti exhibits high corrosion resistance and good protective properties. Thus, composite carbon films could be used as a conductive electrode in various chemical and bio applications.

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Pukha V, Belmesov A, Glukhov A, Khodos I, Khadem M, Kim DE et al. Features of the Conductive Carbon Coatings Formation on Titanium Electrodes Using C₆₀ Ion Beams. In Velichko E, Kapralova V, Karaseov P, Zavjalov S, Angueira P, Andreev S, editors, International Youth Conference on Electronics, Telecommunications and Information Technologies - Proceedings of the YETI 2021. Springer Science and Business Media Deutschland GmbH. 2022. p. 385-394. (Springer Proceedings in Physics). doi: 10.1007/978-3-030-81119-8_41