FeMn Metal Droplet Behavior in the MnO-SiO2-CaO Slag System

Hyoung Soon Jang, Jae Wook Ryu, Il Sohn

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Optimization of the MnO-SiO2-CaO-based slag composition in the FeMn decarburization refining process to minimize metal droplet entrainment has been studied. FeMn spherical droplets with average diameter of 2.5 mm were dispersed within the refining slag of the medium carbon grade ferro-manganese alloy process. Approximately 4.2 pct of the slag existed as FeMn droplets contributing to the overall metal yield loss in the current process. Sedimentation tests of slags with various SiO2 content ranging from 26 to 47 pct using Al2O3 crucibles held at 1773 K (1500 °C) for 30 minutes showed an improvement of the metal/slag separation. Estimated and measured viscosity of the slags showed SiO2 at 32 pct to be optimal for metal/slag separation. Changes in the SiO2 content to 32 pct in actual plant trials allowed significant decrease in the amount of metal droplet entrainment resulting in a decrease of metal in slag to 1.3 pct. Refining times for this optimized slag composition required at least 20 minutes holding for increased separation according to Stokes’ law.

Original languageEnglish
Pages (from-to)606-614
Number of pages9
JournalMetallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
Volume46
Issue number2
DOIs
Publication statusPublished - 2014 Nov 6

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slags
Slags
Metals
metals
refining
Refining
entrainment
manganese alloys
Stokes law
decarburization
Manganese alloys
Decarburization
Crucibles
crucibles
Chemical analysis
Sedimentation
grade
Carbon
Viscosity
viscosity

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

Cite this

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abstract = "Optimization of the MnO-SiO2-CaO-based slag composition in the FeMn decarburization refining process to minimize metal droplet entrainment has been studied. FeMn spherical droplets with average diameter of 2.5 mm were dispersed within the refining slag of the medium carbon grade ferro-manganese alloy process. Approximately 4.2 pct of the slag existed as FeMn droplets contributing to the overall metal yield loss in the current process. Sedimentation tests of slags with various SiO2 content ranging from 26 to 47 pct using Al2O3 crucibles held at 1773 K (1500 °C) for 30 minutes showed an improvement of the metal/slag separation. Estimated and measured viscosity of the slags showed SiO2 at 32 pct to be optimal for metal/slag separation. Changes in the SiO2 content to 32 pct in actual plant trials allowed significant decrease in the amount of metal droplet entrainment resulting in a decrease of metal in slag to 1.3 pct. Refining times for this optimized slag composition required at least 20 minutes holding for increased separation according to Stokes’ law.",
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FeMn Metal Droplet Behavior in the MnO-SiO2-CaO Slag System. / Jang, Hyoung Soon; Ryu, Jae Wook; Sohn, Il.

In: Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, Vol. 46, No. 2, 06.11.2014, p. 606-614.

Research output: Contribution to journalArticle

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