A boat-shaped 1,4-cyclohexadiene-like ring is present in the C60 molecule with a novel σ-type μ3-η1,η2,η1 bonding mode in the clusters 2a and 2b. The change in coordination mode was induced by insertion of an RNC ligand into an Os-Os bond of the π-type C60 complex 1.R = CH2C6H5.
|Number of pages||3|
|Journal||Angewandte Chemie - International Edition|
|Publication status||Published - 2001 Apr 17|
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