First-order Judd-Ofelt optical characterization of DNA-Ln3+ complexes

Bjorn Paulson; Gregor Sauer; Seungwuk Cheon; Sreekantha Reddy Dugasani; Kyunghwan Oh

doi:10.1117/12.2237633

First-order Judd-Ofelt optical characterization of DNA-Ln³⁺ complexes

Bjorn Paulson, Gregor Sauer, Seungwuk Cheon, Sreekantha Reddy Dugasani, Kyunghwan Oh

Department of Physics

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Complexes formed of deoxyribose nucleic acid (DNA) and trivalent lanthanide ions (Ln³⁺) promise a combination of high optical gain and low optical loss in an organic polymer host matrix. However, there has been some dispute about the binding mechanism between the DNA helix and the positively-charged lanthanide ions. Here we introduce an attempt to resolve the mechanism for binding through Judd-Ofelt analysis on DNA-Eu³⁺, DNA-Tb³⁺, and DNA-Sm³⁺ to first order. From initial Judd-Ofelt parameters extrapolations can be made to the line strengths, Einstein coefficients, and fluorescence lifetimes.

Original language	English
Title of host publication	Nanobiosystems
Subtitle of host publication	Processing, Characterization, and Applications IX
Editors	Norihisa Kobayashi, Fahima Ouchen, Ileana Rau
Publisher	SPIE
ISBN (Electronic)	9781510602472
DOIs	https://doi.org/10.1117/12.2237633
Publication status	Published - 2016
Event	Nanobiosystems: Processing, Characterization, and Applications IX - San Diego, United States Duration: 2016 Aug 28 → 2016 Aug 31

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	9928
ISSN (Print)	0277-786X
ISSN (Electronic)	1996-756X

Other

Other	Nanobiosystems: Processing, Characterization, and Applications IX
Country	United States
City	San Diego
Period	16/8/28 → 16/8/31

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

Access to Document

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Paulson, B., Sauer, G., Cheon, S., Dugasani, S. R., & Oh, K. (2016). First-order Judd-Ofelt optical characterization of DNA-Ln³⁺ complexes. In N. Kobayashi, F. Ouchen, & I. Rau (Eds.), Nanobiosystems: Processing, Characterization, and Applications IX [99280N] (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 9928). SPIE. https://doi.org/10.1117/12.2237633

Paulson, Bjorn ; Sauer, Gregor ; Cheon, Seungwuk ; Dugasani, Sreekantha Reddy ; Oh, Kyunghwan. / First-order Judd-Ofelt optical characterization of DNA-Ln³⁺ complexes. Nanobiosystems: Processing, Characterization, and Applications IX. editor / Norihisa Kobayashi ; Fahima Ouchen ; Ileana Rau. SPIE, 2016. (Proceedings of SPIE - The International Society for Optical Engineering).

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title = "First-order Judd-Ofelt optical characterization of DNA-Ln3+ complexes",

abstract = "Complexes formed of deoxyribose nucleic acid (DNA) and trivalent lanthanide ions (Ln3+) promise a combination of high optical gain and low optical loss in an organic polymer host matrix. However, there has been some dispute about the binding mechanism between the DNA helix and the positively-charged lanthanide ions. Here we introduce an attempt to resolve the mechanism for binding through Judd-Ofelt analysis on DNA-Eu3+, DNA-Tb3+, and DNA-Sm3+ to first order. From initial Judd-Ofelt parameters extrapolations can be made to the line strengths, Einstein coefficients, and fluorescence lifetimes.",

author = "Bjorn Paulson and Gregor Sauer and Seungwuk Cheon and Dugasani, {Sreekantha Reddy} and Kyunghwan Oh",

year = "2016",

doi = "10.1117/12.2237633",

language = "English",

series = "Proceedings of SPIE - The International Society for Optical Engineering",

publisher = "SPIE",

editor = "Norihisa Kobayashi and Fahima Ouchen and Ileana Rau",

booktitle = "Nanobiosystems",

address = "United States",

note = "Nanobiosystems: Processing, Characterization, and Applications IX ; Conference date: 28-08-2016 Through 31-08-2016",

}

Paulson, B, Sauer, G, Cheon, S, Dugasani, SR & Oh, K 2016, First-order Judd-Ofelt optical characterization of DNA-Ln³⁺ complexes. in N Kobayashi, F Ouchen & I Rau (eds), Nanobiosystems: Processing, Characterization, and Applications IX., 99280N, Proceedings of SPIE - The International Society for Optical Engineering, vol. 9928, SPIE, Nanobiosystems: Processing, Characterization, and Applications IX, San Diego, United States, 16/8/28. https://doi.org/10.1117/12.2237633

First-order Judd-Ofelt optical characterization of DNA-Ln³⁺ complexes. / Paulson, Bjorn; Sauer, Gregor; Cheon, Seungwuk; Dugasani, Sreekantha Reddy; Oh, Kyunghwan.

Nanobiosystems: Processing, Characterization, and Applications IX. ed. / Norihisa Kobayashi; Fahima Ouchen; Ileana Rau. SPIE, 2016. 99280N (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 9928).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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AB - Complexes formed of deoxyribose nucleic acid (DNA) and trivalent lanthanide ions (Ln3+) promise a combination of high optical gain and low optical loss in an organic polymer host matrix. However, there has been some dispute about the binding mechanism between the DNA helix and the positively-charged lanthanide ions. Here we introduce an attempt to resolve the mechanism for binding through Judd-Ofelt analysis on DNA-Eu3+, DNA-Tb3+, and DNA-Sm3+ to first order. From initial Judd-Ofelt parameters extrapolations can be made to the line strengths, Einstein coefficients, and fluorescence lifetimes.

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