Fluorescent nanostructures from aromatic diblock copolymers via atom transfer radical polymerization

Jungmok You, Eunkyoung Kim

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Well-defined fluorophore (anthracene or pyrene) containing copolymers were synthesized via atom transfer radical polymerization (ATRP) using methyl methacrylate (MMA) and fluorophore bound methacrylate (AntMA or PyMA). The copolymers exhibited clearly distinct thermal and optical properties, in terms of glass transition temperature (Tg) and emission spectrum, depending on the polymer structures. Moreover self-assembly properties of the copolymers affected the formation of the polymer nanostructures at condensed phase, to distinguish the random against block copolymers. The antracene containing random copolymer had a single Tg value while antracene containing block copolymer had two Tg values. In addition, sharp fluorescence peaks (398, 416 and 439 nm) werer observed in the random copolymer of antracene. In contrast, the anthracene containing block copolymer showed a broad tailing of the peak reaching ∼550 nm. Interestingly, the copolymers having both randomly distributed anthracene units and consecutively connected pyrene units exhibited sharp emission at 398, 416, and 442 nm originated from the antracene unit and pyrene excimer emission at 482 nm. More importantly, well ordered nanopore films and nano scale micelle structures, originated from the self-assembly of antracene or pyrene block unit, were formed in block copolymers, while any type of an ordered structure was not found from the random copolymers. Therefore fluorescent nanostructures could be well-controlled by the polymers structures containing antracene and pyrene units, which might be widely useful for the development of novel photonics, optoelectronics, and sensor devices.

Original languageEnglish
Pages (from-to)10927-10934
Number of pages8
JournalJournal of Nanoscience and Nanotechnology
Volume16
Issue number10
DOIs
Publication statusPublished - 2016 Oct 1

Fingerprint

Nanostructures
Atom transfer radical polymerization
Polymerization
Block copolymers
copolymers
Pyrene
Copolymers
polymerization
pyrenes
block copolymers
Polymers
Anthracene
Methacrylates
atoms
anthracene
Fluorophores
Nanopores
Optics and Photonics
Self assembly
self assembly

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Biomedical Engineering
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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abstract = "Well-defined fluorophore (anthracene or pyrene) containing copolymers were synthesized via atom transfer radical polymerization (ATRP) using methyl methacrylate (MMA) and fluorophore bound methacrylate (AntMA or PyMA). The copolymers exhibited clearly distinct thermal and optical properties, in terms of glass transition temperature (Tg) and emission spectrum, depending on the polymer structures. Moreover self-assembly properties of the copolymers affected the formation of the polymer nanostructures at condensed phase, to distinguish the random against block copolymers. The antracene containing random copolymer had a single Tg value while antracene containing block copolymer had two Tg values. In addition, sharp fluorescence peaks (398, 416 and 439 nm) werer observed in the random copolymer of antracene. In contrast, the anthracene containing block copolymer showed a broad tailing of the peak reaching ∼550 nm. Interestingly, the copolymers having both randomly distributed anthracene units and consecutively connected pyrene units exhibited sharp emission at 398, 416, and 442 nm originated from the antracene unit and pyrene excimer emission at 482 nm. More importantly, well ordered nanopore films and nano scale micelle structures, originated from the self-assembly of antracene or pyrene block unit, were formed in block copolymers, while any type of an ordered structure was not found from the random copolymers. Therefore fluorescent nanostructures could be well-controlled by the polymers structures containing antracene and pyrene units, which might be widely useful for the development of novel photonics, optoelectronics, and sensor devices.",
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Fluorescent nanostructures from aromatic diblock copolymers via atom transfer radical polymerization. / You, Jungmok; Kim, Eunkyoung.

In: Journal of Nanoscience and Nanotechnology, Vol. 16, No. 10, 01.10.2016, p. 10927-10934.

Research output: Contribution to journalArticle

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