Fluorographenes via thermal exfoliation of graphite oxide in SF 6, SF4 and MoF6 atmospheres

Hwee Ling Poh, Zdeněk Sofer, Kateřina Klímová, Martin Pumera

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Functionalization of graphene with heteroatoms is of paramount interest. Doping of graphene materials with electron withdrawing groups leads to the opening of the band gap which further results in a change of its electronic and electrochemical properties. Fluorine exhibits the largest electronegativity and thus it is expected that fluorographenes will have significantly different properties from graphene. Fluorinated graphene was prepared by a scalable method using thermal treatments (at different temperatures) or microwave plasma exfoliation of graphite oxides (prepared via chlorate or permanganate routes) in atmospheres containing SF6, SF4 or MoF6 fluorination agents. We characterized the resulting fluorographenes by scanning electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, combustible elemental analysis and cyclic voltammetry. It was observed that with increasing fluorine content the heterogeneous electron transfer rates increased. The scalable fluorination of graphene with relatively low-toxic agents which yields high-performance electrochemical materials should find many applications in electrochemical devices, such as sensors or supercapacitors.

Original languageEnglish
Pages (from-to)5198-5207
Number of pages10
JournalJournal of Materials Chemistry C
Volume2
Issue number26
DOIs
Publication statusPublished - 2014 Jul 14

Fingerprint

Graphite
Oxides
Graphene
Fluorination
Fluorine
Electronegativity
Chlorates
Electrons
Electrochemical properties
Electronic properties
Poisons
Cyclic voltammetry
Raman spectroscopy
Energy gap
X ray photoelectron spectroscopy
Heat treatment
Microwaves
Doping (additives)
Hot Temperature
6-trifluoroacetamido-4,5-dihydroxy-3-piperidinecarboxylic acid

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Cite this

Poh, Hwee Ling ; Sofer, Zdeněk ; Klímová, Kateřina ; Pumera, Martin. / Fluorographenes via thermal exfoliation of graphite oxide in SF 6, SF4 and MoF6 atmospheres. In: Journal of Materials Chemistry C. 2014 ; Vol. 2, No. 26. pp. 5198-5207.
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Fluorographenes via thermal exfoliation of graphite oxide in SF 6, SF4 and MoF6 atmospheres. / Poh, Hwee Ling; Sofer, Zdeněk; Klímová, Kateřina; Pumera, Martin.

In: Journal of Materials Chemistry C, Vol. 2, No. 26, 14.07.2014, p. 5198-5207.

Research output: Contribution to journalArticle

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