Fluorometric detection of nitroaromatics by fluorescent lead complexes: A spectroscopic assessment of detection mechanism

Tanmay Chattopadhyay, Sourav Chatterjee, Ishani Majumder, Soumen Ghosh, Sangee Yoon, Eunji Sim

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Three Schiff base ligands such as 2‑[(2‑Hydroxy‑3‑methoxy‑benzylidene)‑amino]‑2‑hydroxymethyl‑propane‑1,3‑diol (HL1), 2‑[(2‑Hydroxy‑benzylidene)‑amino]‑2‑hydroxymethyl‑propane‑1,3‑diol (HL2), 2‑[(3,5‑Dichloro‑2‑hydroxy‑benzylidene)‑amino]‑2‑hydroxymethyl‑propane‑1,3‑diol (HL3) have been synthesized by condensation of aldehydes (such as 3,5‑Dichloro‑2‑hydroxy benzaldehyde, 2‑Hydroxy‑benzaldehyde, and 2‑Hydroxy‑3‑methoxy‑benzaldehyde) with Tris‑(hydroxymethyl)amino methane and characterized by IR, UV–vis and 1H NMR spectroscopy. Then all these three ligands have been used to prepare Pb(II) complexes by reaction with lead(II) acetate tri-hydrate in methanol. In view of analytical and spectral (IR, UV–vis and Mass) studies, it has been concluded that, except HL2, other two ligands form 1:1 metal complexes (1 and 3) with lead. Between two complexes, complex 3 is highly fluorescent and this property has been used to identify the pollutant nitroaromatics. Finally, the quenching mechanism has been established by means of spectroscopic investigation.

Original languageEnglish
Pages (from-to)222-229
Number of pages8
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume194
DOIs
Publication statusPublished - 2018 Apr 5

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Instrumentation
  • Spectroscopy

Fingerprint Dive into the research topics of 'Fluorometric detection of nitroaromatics by fluorescent lead complexes: A spectroscopic assessment of detection mechanism'. Together they form a unique fingerprint.

Cite this