Foldamer-based helicate displaying reversible switching between two distinct conformers

Hae Geun Jeon, Hyun Kyung Lee, Seungwon Lee, Kyu Sung Jeong

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.

Original languageEnglish
Pages (from-to)5740-5743
Number of pages4
JournalChemical Communications
Volume54
Issue number45
DOIs
Publication statusPublished - 2018

Bibliographical note

Funding Information:
This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607). The authors acknowledge the Pohang Accelerator Laboratory (PAL) for beam line use (2017-3rd-2D-008).

Funding Information:
This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607).

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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