Foldamer-based helicate displaying reversible switching between two distinct conformers

Hae Geun Jeon; Hyun Kyung Lee; Seungwon Lee; Kyu Sung Jeong

doi:10.1039/c8cc02758g

Foldamer-based helicate displaying reversible switching between two distinct conformers

Hae Geun Jeon, Hyun Kyung Lee, Seungwon Lee, Kyu Sung Jeong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.

Original language	English
Pages (from-to)	5740-5743
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	45
DOIs	https://doi.org/10.1039/c8cc02758g
Publication status	Published - 2018

Bibliographical note

Funding Information:
This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607). The authors acknowledge the Pohang Accelerator Laboratory (PAL) for beam line use (2017-3rd-2D-008).

Funding Information:
This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607).

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c8cc02758g

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title = "Foldamer-based helicate displaying reversible switching between two distinct conformers",

abstract = "A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.",

author = "Jeon, {Hae Geun} and Lee, {Hyun Kyung} and Seungwon Lee and Jeong, {Kyu Sung}",

note = "Funding Information: This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607). The authors acknowledge the Pohang Accelerator Laboratory (PAL) for beam line use (2017-3rd-2D-008). Funding Information: This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607).",

year = "2018",

doi = "10.1039/c8cc02758g",

language = "English",

volume = "54",

pages = "5740--5743",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Jeon, Hae Geun

AU - Lee, Hyun Kyung

AU - Lee, Seungwon

AU - Jeong, Kyu Sung

N1 - Funding Information: This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607). The authors acknowledge the Pohang Accelerator Laboratory (PAL) for beam line use (2017-3rd-2D-008). Funding Information: This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607).

PY - 2018

Y1 - 2018

N2 - A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.

AB - A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.

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