Abstract
A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.
Original language | English |
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Pages (from-to) | 5740-5743 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 54 |
Issue number | 45 |
DOIs | |
Publication status | Published - 2018 |
Bibliographical note
Funding Information:This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607). The authors acknowledge the Pohang Accelerator Laboratory (PAL) for beam line use (2017-3rd-2D-008).
Funding Information:
This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2015R1A2A1A10053607).
Publisher Copyright:
© 2018 The Royal Society of Chemistry.
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry