Formation efficiency of one-dimensional nanostructured titanium oxide affected by the structure and composition of titanate precursor: A mechanism study

Mi Jeong Paek, Hyung Wook Ha, Tae Woo Kim, Sang Jin Moon, Jin Ook Baeg, Jin Ho Choy, Seong Ju Hwang

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The formation mechanism and atomic arrangement of one-dimensional (ID) nanostructured titanates have been systematically investigated with combinative spectroscopic and microscopic analyses. First of all, the influence of the interlayer distances of the lepidocrocite-type titanate precursor on the formation efficiency of ID nanobelts has been studied, clearly demonstrating that the increase of basal spacing upon the protonation does not promote the formation of ID nanostructures. This finding did not support the previously proposed exfoliation mechanism of the layered titanate precursor. Of special interest is that the poor efficiency of the protonated titanate as a precursor could be enhanced by Fe substitution, underscoring the importance of precursor dissolution. According to time-dependent electron microscopic analyses, the hydrothermal alkali treatment initially gave rise not only to a decrease in the particle size of the precursor but also to the formation of ID titanate nanobelts with lepidocrocite structure, which was followed by the dissolution of the initially formed nanobelts, the appearance of bigger layer-shape crystallites, and their splitting into ID nanobelts with trititanate structure. This finding provided strong support for the dissolution/recrystallization model, in which the dissolution of the precursor plays a crucial role in the formation of ID nanostructured titanate. Electron diffraction, Ti K-edge X-ray absorption near-edge structure, and micro-Raman spectroscopy clearly demonstrated that the ID nanobelts prepared by the extended hydrothermal treatment (i.e., 48 h) and layer-shaped intermediate commonly crystallize with trititanate-type structure, which is clearly distinguishable from the lepidocrocite structure of the precursor. On the basis of all the present experimental findings, we are able to conclude that the ID titanate nanobelts with trititanate structure were produced via a splitting of intermediate layered crystallites formed from the dissolved species.

Original languageEnglish
Pages (from-to)15966-15972
Number of pages7
JournalJournal of Physical Chemistry C
Volume112
Issue number41
DOIs
Publication statusPublished - 2008 Oct 16

Fingerprint

Nanobelts
Titanium oxides
titanium oxides
dissolving
Dissolution
Chemical analysis
crystallites
Crystallites
titanates
Protonation
X ray absorption
Alkalies
interlayers
alkalies
Electron diffraction
electron diffraction
Raman spectroscopy
spacing
titanium dioxide
Nanostructures

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Paek, Mi Jeong ; Ha, Hyung Wook ; Kim, Tae Woo ; Moon, Sang Jin ; Baeg, Jin Ook ; Choy, Jin Ho ; Hwang, Seong Ju. / Formation efficiency of one-dimensional nanostructured titanium oxide affected by the structure and composition of titanate precursor : A mechanism study. In: Journal of Physical Chemistry C. 2008 ; Vol. 112, No. 41. pp. 15966-15972.
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abstract = "The formation mechanism and atomic arrangement of one-dimensional (ID) nanostructured titanates have been systematically investigated with combinative spectroscopic and microscopic analyses. First of all, the influence of the interlayer distances of the lepidocrocite-type titanate precursor on the formation efficiency of ID nanobelts has been studied, clearly demonstrating that the increase of basal spacing upon the protonation does not promote the formation of ID nanostructures. This finding did not support the previously proposed exfoliation mechanism of the layered titanate precursor. Of special interest is that the poor efficiency of the protonated titanate as a precursor could be enhanced by Fe substitution, underscoring the importance of precursor dissolution. According to time-dependent electron microscopic analyses, the hydrothermal alkali treatment initially gave rise not only to a decrease in the particle size of the precursor but also to the formation of ID titanate nanobelts with lepidocrocite structure, which was followed by the dissolution of the initially formed nanobelts, the appearance of bigger layer-shape crystallites, and their splitting into ID nanobelts with trititanate structure. This finding provided strong support for the dissolution/recrystallization model, in which the dissolution of the precursor plays a crucial role in the formation of ID nanostructured titanate. Electron diffraction, Ti K-edge X-ray absorption near-edge structure, and micro-Raman spectroscopy clearly demonstrated that the ID nanobelts prepared by the extended hydrothermal treatment (i.e., 48 h) and layer-shaped intermediate commonly crystallize with trititanate-type structure, which is clearly distinguishable from the lepidocrocite structure of the precursor. On the basis of all the present experimental findings, we are able to conclude that the ID titanate nanobelts with trititanate structure were produced via a splitting of intermediate layered crystallites formed from the dissolved species.",
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Formation efficiency of one-dimensional nanostructured titanium oxide affected by the structure and composition of titanate precursor : A mechanism study. / Paek, Mi Jeong; Ha, Hyung Wook; Kim, Tae Woo; Moon, Sang Jin; Baeg, Jin Ook; Choy, Jin Ho; Hwang, Seong Ju.

In: Journal of Physical Chemistry C, Vol. 112, No. 41, 16.10.2008, p. 15966-15972.

Research output: Contribution to journalArticle

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AU - Paek, Mi Jeong

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AU - Kim, Tae Woo

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AU - Hwang, Seong Ju

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AB - The formation mechanism and atomic arrangement of one-dimensional (ID) nanostructured titanates have been systematically investigated with combinative spectroscopic and microscopic analyses. First of all, the influence of the interlayer distances of the lepidocrocite-type titanate precursor on the formation efficiency of ID nanobelts has been studied, clearly demonstrating that the increase of basal spacing upon the protonation does not promote the formation of ID nanostructures. This finding did not support the previously proposed exfoliation mechanism of the layered titanate precursor. Of special interest is that the poor efficiency of the protonated titanate as a precursor could be enhanced by Fe substitution, underscoring the importance of precursor dissolution. According to time-dependent electron microscopic analyses, the hydrothermal alkali treatment initially gave rise not only to a decrease in the particle size of the precursor but also to the formation of ID titanate nanobelts with lepidocrocite structure, which was followed by the dissolution of the initially formed nanobelts, the appearance of bigger layer-shape crystallites, and their splitting into ID nanobelts with trititanate structure. This finding provided strong support for the dissolution/recrystallization model, in which the dissolution of the precursor plays a crucial role in the formation of ID nanostructured titanate. Electron diffraction, Ti K-edge X-ray absorption near-edge structure, and micro-Raman spectroscopy clearly demonstrated that the ID nanobelts prepared by the extended hydrothermal treatment (i.e., 48 h) and layer-shaped intermediate commonly crystallize with trititanate-type structure, which is clearly distinguishable from the lepidocrocite structure of the precursor. On the basis of all the present experimental findings, we are able to conclude that the ID titanate nanobelts with trititanate structure were produced via a splitting of intermediate layered crystallites formed from the dissolved species.

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