We investigated, for the first time, the conditions where a thermoplastic conductive composite can exhibit completely reversible stretchability at high elongational strains (= 1.8). We studied a composite of Au nanosheets and a polystyrene-block-polybutadiene-block-polystyrene block copolymer as an example. The composite had an outstandingly low sheet resistance (0.45 /sq). We found that when a thin thermoplastic composite film is placed on a relatively thicker chemically cross-linked elastomer film, it can follow the reversible elastic behavior of the bottom elastomer. Such elasticity comes from the restoration of the block copolymer microstructure. The strong adhesion of the thermoplastic polymer to the metallic fillers is advantageous in the fabrication of mechanically robust, highly conductive, stretchable electrodes. The chemical stability of the Au composite was used to fabricate high luminescence, stretchable electrochemiluminescence displays with a conventional top-bottom electrode setup and with a horizontal electrode setup.
Bibliographical noteFunding Information:
This work was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT (MSIT) (2017R1A4A1015811) and Pohang Steel Corporation (POSCO) through the Green Science Program (project no. 2015Y060). Experiments at PLS-II 6D UNIST-PAL beamline were supported in part by the UNIST Central Research Facilities, MSIP, and POSTECH. Also, this work was supported by the Technology Innovation Program or Industrial Strategic Technology Development Program (10077533, Development of robotic manipulation algorithm for grasping/assembling with the machine learning using visual and tactile sensing information) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea).
© 2017 American Chemical Society.
All Science Journal Classification (ASJC) codes
- Materials Science(all)