Fully organic CO2 absorbent obtained by a Schiff base reaction between branched poly(ethyleneimine) and glutaraldehyde

Ki Seob Hwang, Hee Young Park, Jung Hyun Kim, Jun Young Lee

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

We used a water-in-oil emulsification method to prepare particulate CO2 absorbents from branched poly(ethyleneimine) (PEI), utilizing 13C nuclear magnetic resonance spectroscopy to determine the amount of free PEI NH2 groups and thus calculate the required cross-linker amount. The functional groups and reactivity of branched PEI particles were characterized by Fourier transform infrared spectroscopy, and their CO2 absorption capacity was determined by thermogravimetric analysis. Dynamic light scattering measurements showed that the synthesized particles exhibited sizes of 0.2-2 μm and high surface areas, which resulted in high CO2 absorption capacities of up to 2.18 mmol CO2 per gram sorbent at 75 °C.

Original languageEnglish
Pages (from-to)798-804
Number of pages7
JournalKorean Journal of Chemical Engineering
Volume35
Issue number3
DOIs
Publication statusPublished - 2018 Mar 1

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Polyetherimides
Schiff Bases
Glutaral
Emulsification
Dynamic light scattering
Sorbents
Functional groups
Nuclear magnetic resonance spectroscopy
Fourier transform infrared spectroscopy
Thermogravimetric analysis
Oils
Particle size
Water
aziridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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abstract = "We used a water-in-oil emulsification method to prepare particulate CO2 absorbents from branched poly(ethyleneimine) (PEI), utilizing 13C nuclear magnetic resonance spectroscopy to determine the amount of free PEI NH2 groups and thus calculate the required cross-linker amount. The functional groups and reactivity of branched PEI particles were characterized by Fourier transform infrared spectroscopy, and their CO2 absorption capacity was determined by thermogravimetric analysis. Dynamic light scattering measurements showed that the synthesized particles exhibited sizes of 0.2-2 μm and high surface areas, which resulted in high CO2 absorption capacities of up to 2.18 mmol CO2 per gram sorbent at 75 °C.",
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Fully organic CO2 absorbent obtained by a Schiff base reaction between branched poly(ethyleneimine) and glutaraldehyde. / Hwang, Ki Seob; Park, Hee Young; Kim, Jung Hyun; Lee, Jun Young.

In: Korean Journal of Chemical Engineering, Vol. 35, No. 3, 01.03.2018, p. 798-804.

Research output: Contribution to journalArticle

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