Functional Protection of Exfoliated Black Phosphorus by Noncovalent Modification with Anthraquinone

Rui Gusmão, Zdeněk Sofer, Martin Pumera

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39 Citations (Scopus)

Abstract

Few and monolayer black phosphorus (phosphorene) is currently an intensively researched material. Shear exfoliated black phosphorus (BPSE) nanosheets were functionalized with the redox active antraquinone (AQ) that can provide additional charge storage capacity. The noncovalent interaction of BP with AQ occurs due to van der Waals interactions. X-ray photoelectron spectroscopy results show that AQ coverage of BPSE nanosheets led to a stabilization against BPSE degradation. Electrochemistry of the BPSE-AQ shows that AQ is stably anchored onto BPSE and exhibits redox peaks stable for more than 100 cycles. The surface coverage by AQ on BPSE is estimated to be 1.25 nmol AQ/mg BP and electron-transfer rate constant (kET) of 33 s-1. Furthermore, the proposed modification greatly increases the gravimetric capacitance of BPSE-AQ with respect to the starting BPbulk. Such coating of BP not only protects BP from degradation but also brings electroactive functionality to this two-dimensionally layered material.

Original languageEnglish
Pages (from-to)5666-5673
Number of pages8
JournalACS Nano
Volume12
Issue number6
DOIs
Publication statusPublished - 2018 Jun 26

Bibliographical note

Funding Information:
Z.S. is supported by Czech Science Foundation (GACR No. 17-11456S). This work was created with the financial support of the Neuron Foundation for science support and the Advanced Functional Nanorobots project (reg. no. CZ.02.1.01/0.0/0.0/15_003/0000444 financed by the EFRR). The authors would like to thank F. Novotný for his assistance with the optical profilometer initial experiments.

Publisher Copyright:
© 2018 American Chemical Society.

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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