Generation of high pretilt angles of nematic liquid crystal (5CB) on rubbed organic solvent soluble polyimide surfaces with helical backbone structure and trifluoromethyl moieties

Dae Shik Seo, Michinori Nishikawa, Shunsuke Kobayashi

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

High pretilt angles of nematic liquid crystals (NLC) have been successfully generated on rubbed organic solvent soluble polyimide (PI) surfaces with a helical backbone structure and trifluoromethyl moieties. We have found that the pretilt angle of in 4-n-penty-4ʹ-cyanobiphenyl (5CB) on rubbed PI surfaces with trifluoromethyl moieties attached to the lateral benzene rings is larger compared to that on rubbed PI surfaces with trifluoromethyl moieties attached to the polymer backbone. The observed pretilt angle of 5CB on unidirectionally rubbed PI surfaces with trifluoromethyl moieties attached to the lateral benzene rings is about 15 degrees in the wide rubbing region. From these results, it is expected that the microscopic surface structure of the polymer strongly contributes to the pretilt angle generation of the LCs at the surface.

Original languageEnglish
Pages (from-to)515-517
Number of pages3
JournalLiquid Crystals
Volume22
Issue number4
DOIs
Publication statusPublished - 1997 Jan 1

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Nematic liquid crystals
polyimides
Polyimides
Organic solvents
liquid crystals
Benzene
Polymers
benzene
Surface structure
rings
polymers

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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abstract = "High pretilt angles of nematic liquid crystals (NLC) have been successfully generated on rubbed organic solvent soluble polyimide (PI) surfaces with a helical backbone structure and trifluoromethyl moieties. We have found that the pretilt angle of in 4-n-penty-4ʹ-cyanobiphenyl (5CB) on rubbed PI surfaces with trifluoromethyl moieties attached to the lateral benzene rings is larger compared to that on rubbed PI surfaces with trifluoromethyl moieties attached to the polymer backbone. The observed pretilt angle of 5CB on unidirectionally rubbed PI surfaces with trifluoromethyl moieties attached to the lateral benzene rings is about 15 degrees in the wide rubbing region. From these results, it is expected that the microscopic surface structure of the polymer strongly contributes to the pretilt angle generation of the LCs at the surface.",
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Generation of high pretilt angles of nematic liquid crystal (5CB) on rubbed organic solvent soluble polyimide surfaces with helical backbone structure and trifluoromethyl moieties. / Seo, Dae Shik; Nishikawa, Michinori; Kobayashi, Shunsuke.

In: Liquid Crystals, Vol. 22, No. 4, 01.01.1997, p. 515-517.

Research output: Contribution to journalArticle

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