Geomimetic Hydrothermal Synthesis of Polyimide-Based Covalent Organic Frameworks

Taehyung Kim; Se Hun Joo; Jintaek Gong; Sungho Choi; Ju Hong Min; Yongchul Kim; Geunsik Lee; Eunji Lee; Soojin Park; Sang Kyu Kwak; Hee Seung Lee; Byeong Su Kim

doi:10.1002/anie.202113780

Geomimetic Hydrothermal Synthesis of Polyimide-Based Covalent Organic Frameworks

Taehyung Kim, Se Hun Joo, Jintaek Gong, Sungho Choi, Ju Hong Min, Yongchul Kim, Geunsik Lee, Eunji Lee, Soojin Park, Sang Kyu Kwak, Hee Seung Lee, Byeong Su Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Despite its abundance, water is not widely used as a medium for organic reactions. However, under geothermal conditions, water exhibits unique physicochemical properties, such as viscosity and a dielectric constant, and the ionic product become similar to those of common organic solvents. We have synthesized highly crystalline polyimide-based covalent organic frameworks (PICs) under geomimetic hydrothermal conditions. By exploiting triphenylene-2,3,6,7,10,11-hexacarboxylic acid in combination with various aromatic diamines, PICs with various pore dimensions and crystallinities were synthesized. XRD, FT-IR, and DFT calculations revealed that the solubility of the oligomeric intermediates under hydrothermal conditions affected the stacking structures of the crystalline PICs. Furthermore, the synthesized PICs demonstrate promising potential as an anode material in lithium-ion batteries owing to its unique redox-active properties and high surface area.

Original language	English
Article number	e202113780
Journal	Angewandte Chemie - International Edition
Volume	61
Issue number	4
DOIs	https://doi.org/10.1002/anie.202113780
Publication status	Published - 2022 Jan 21

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF-2021R1A2C3004978 and NRF-2018R1A5A1025208). The synchrotron powder X-ray diffraction data for structural analysis were collected from the 9B beamline at the Pohang Accelerator Laboratory (Pohang, Republic of Korea). S.K.K. acknowledges financial support from the C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF-2018M3D3A1A01055761). S.K.K. and G.L. acknowledge the computational calculations supported by the National Supercomputing Center with supercomputing resources including technical support (KSC-2021-CRE-0125 and KSC-2021-CRE-0188), UNIST-HPC, and UNIST supercomputing center.

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF‐2021R1A2C3004978 and NRF‐2018R1A5A1025208). The synchrotron powder X‐ray diffraction data for structural analysis were collected from the 9B beamline at the Pohang Accelerator Laboratory (Pohang, Republic of Korea). S.K.K. acknowledges financial support from the C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF‐2018M3D3A1A01055761). S.K.K. and G.L. acknowledge the computational calculations supported by the National Supercomputing Center with supercomputing resources including technical support (KSC‐2021‐CRE‐0125 and KSC‐2021‐CRE‐0188), UNIST‐HPC, and UNIST supercomputing center.

Publisher Copyright:
© 2021 Wiley-VCH GmbH

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/anie.202113780

Cite this

@article{53f2eb38a2d24dfdb1aa194e235232c3,

title = "Geomimetic Hydrothermal Synthesis of Polyimide-Based Covalent Organic Frameworks",

abstract = "Despite its abundance, water is not widely used as a medium for organic reactions. However, under geothermal conditions, water exhibits unique physicochemical properties, such as viscosity and a dielectric constant, and the ionic product become similar to those of common organic solvents. We have synthesized highly crystalline polyimide-based covalent organic frameworks (PICs) under geomimetic hydrothermal conditions. By exploiting triphenylene-2,3,6,7,10,11-hexacarboxylic acid in combination with various aromatic diamines, PICs with various pore dimensions and crystallinities were synthesized. XRD, FT-IR, and DFT calculations revealed that the solubility of the oligomeric intermediates under hydrothermal conditions affected the stacking structures of the crystalline PICs. Furthermore, the synthesized PICs demonstrate promising potential as an anode material in lithium-ion batteries owing to its unique redox-active properties and high surface area.",

author = "Taehyung Kim and Joo, {Se Hun} and Jintaek Gong and Sungho Choi and Min, {Ju Hong} and Yongchul Kim and Geunsik Lee and Eunji Lee and Soojin Park and Kwak, {Sang Kyu} and Lee, {Hee Seung} and Kim, {Byeong Su}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (NRF-2021R1A2C3004978 and NRF-2018R1A5A1025208). The synchrotron powder X-ray diffraction data for structural analysis were collected from the 9B beamline at the Pohang Accelerator Laboratory (Pohang, Republic of Korea). S.K.K. acknowledges financial support from the C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF-2018M3D3A1A01055761). S.K.K. and G.L. acknowledge the computational calculations supported by the National Supercomputing Center with supercomputing resources including technical support (KSC-2021-CRE-0125 and KSC-2021-CRE-0188), UNIST-HPC, and UNIST supercomputing center. Funding Information: This work was supported by the National Research Foundation of Korea (NRF‐2021R1A2C3004978 and NRF‐2018R1A5A1025208). The synchrotron powder X‐ray diffraction data for structural analysis were collected from the 9B beamline at the Pohang Accelerator Laboratory (Pohang, Republic of Korea). S.K.K. acknowledges financial support from the C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF‐2018M3D3A1A01055761). S.K.K. and G.L. acknowledge the computational calculations supported by the National Supercomputing Center with supercomputing resources including technical support (KSC‐2021‐CRE‐0125 and KSC‐2021‐CRE‐0188), UNIST‐HPC, and UNIST supercomputing center. Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",

year = "2022",

month = jan,

day = "21",

doi = "10.1002/anie.202113780",

language = "English",

volume = "61",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "4",

}

TY - JOUR

T1 - Geomimetic Hydrothermal Synthesis of Polyimide-Based Covalent Organic Frameworks

AU - Kim, Taehyung

AU - Joo, Se Hun

AU - Gong, Jintaek

AU - Choi, Sungho

AU - Min, Ju Hong

AU - Kim, Yongchul

AU - Lee, Geunsik

AU - Lee, Eunji

AU - Park, Soojin

AU - Kwak, Sang Kyu

AU - Lee, Hee Seung

AU - Kim, Byeong Su

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (NRF-2021R1A2C3004978 and NRF-2018R1A5A1025208). The synchrotron powder X-ray diffraction data for structural analysis were collected from the 9B beamline at the Pohang Accelerator Laboratory (Pohang, Republic of Korea). S.K.K. acknowledges financial support from the C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF-2018M3D3A1A01055761). S.K.K. and G.L. acknowledge the computational calculations supported by the National Supercomputing Center with supercomputing resources including technical support (KSC-2021-CRE-0125 and KSC-2021-CRE-0188), UNIST-HPC, and UNIST supercomputing center. Funding Information: This work was supported by the National Research Foundation of Korea (NRF‐2021R1A2C3004978 and NRF‐2018R1A5A1025208). The synchrotron powder X‐ray diffraction data for structural analysis were collected from the 9B beamline at the Pohang Accelerator Laboratory (Pohang, Republic of Korea). S.K.K. acknowledges financial support from the C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF‐2018M3D3A1A01055761). S.K.K. and G.L. acknowledge the computational calculations supported by the National Supercomputing Center with supercomputing resources including technical support (KSC‐2021‐CRE‐0125 and KSC‐2021‐CRE‐0188), UNIST‐HPC, and UNIST supercomputing center. Publisher Copyright: © 2021 Wiley-VCH GmbH

PY - 2022/1/21

Y1 - 2022/1/21

N2 - Despite its abundance, water is not widely used as a medium for organic reactions. However, under geothermal conditions, water exhibits unique physicochemical properties, such as viscosity and a dielectric constant, and the ionic product become similar to those of common organic solvents. We have synthesized highly crystalline polyimide-based covalent organic frameworks (PICs) under geomimetic hydrothermal conditions. By exploiting triphenylene-2,3,6,7,10,11-hexacarboxylic acid in combination with various aromatic diamines, PICs with various pore dimensions and crystallinities were synthesized. XRD, FT-IR, and DFT calculations revealed that the solubility of the oligomeric intermediates under hydrothermal conditions affected the stacking structures of the crystalline PICs. Furthermore, the synthesized PICs demonstrate promising potential as an anode material in lithium-ion batteries owing to its unique redox-active properties and high surface area.

AB - Despite its abundance, water is not widely used as a medium for organic reactions. However, under geothermal conditions, water exhibits unique physicochemical properties, such as viscosity and a dielectric constant, and the ionic product become similar to those of common organic solvents. We have synthesized highly crystalline polyimide-based covalent organic frameworks (PICs) under geomimetic hydrothermal conditions. By exploiting triphenylene-2,3,6,7,10,11-hexacarboxylic acid in combination with various aromatic diamines, PICs with various pore dimensions and crystallinities were synthesized. XRD, FT-IR, and DFT calculations revealed that the solubility of the oligomeric intermediates under hydrothermal conditions affected the stacking structures of the crystalline PICs. Furthermore, the synthesized PICs demonstrate promising potential as an anode material in lithium-ion batteries owing to its unique redox-active properties and high surface area.

UR - http://www.scopus.com/inward/record.url?scp=85120615390&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85120615390&partnerID=8YFLogxK

U2 - 10.1002/anie.202113780

DO - 10.1002/anie.202113780

M3 - Article

C2 - 34708501

AN - SCOPUS:85120615390

SN - 1433-7851

VL - 61

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 4

M1 - e202113780

ER -

Geomimetic Hydrothermal Synthesis of Polyimide-Based Covalent Organic Frameworks

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this