Graphene Derivative As a Highly Efficient Nitrosonium Source: A Reusable Catalyst for Diazotization and Coupling Reaction

Dattatray A. Pethsangave, Rahul V. Khose, Atul C. Chaskar, Seong Chan Jun, Surajit Some

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

An efficient and a simple approach for the synthesis of azo dyes have been developed by the diazo coupling reactions of active aromatic compounds in the presence of in-situ nitrite functionalized graphene oxide polyvinyl alcohol GO-PVA composite as a highly efficient nitrosonium ion source. This methodology was objected to defeat the limitations of the earlier reported method such as use of acids, alkalis and toxic solvents, to reduce the stability of diazonium salts at room temperature, modest yields and long reaction time. Additionally, the attractive advantages of the process are that it incorporated mild conditions with excellent yield, simple product isolation process, fastest reaction time and recyclability of catalyst. The isolated products were characterized by FT-IR spectrum, UV-spectroscopy and 1H-NMR. The as-prepared composites were confirmed by UV-Visible, XRD, XPS, FT-IR spectrum, SEM and TGA analysis.

Original languageEnglish
Pages (from-to)6933-6940
Number of pages8
JournalChemistrySelect
Volume1
Issue number21
DOIs
Publication statusPublished - 2016 Jan 1

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Azo Compounds
Derivatives
Polyvinyl Alcohol
Catalysts
Aromatic compounds
Poisons
Composite materials
Alkalies
Ion sources
Nitrites
Ultraviolet spectroscopy
Oxides
X ray photoelectron spectroscopy
Salts
Nuclear magnetic resonance
Scanning electron microscopy
Acids
Temperature
nitrosonium ion

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Pethsangave, Dattatray A. ; Khose, Rahul V. ; Chaskar, Atul C. ; Jun, Seong Chan ; Some, Surajit. / Graphene Derivative As a Highly Efficient Nitrosonium Source : A Reusable Catalyst for Diazotization and Coupling Reaction. In: ChemistrySelect. 2016 ; Vol. 1, No. 21. pp. 6933-6940.
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Graphene Derivative As a Highly Efficient Nitrosonium Source : A Reusable Catalyst for Diazotization and Coupling Reaction. / Pethsangave, Dattatray A.; Khose, Rahul V.; Chaskar, Atul C.; Jun, Seong Chan; Some, Surajit.

In: ChemistrySelect, Vol. 1, No. 21, 01.01.2016, p. 6933-6940.

Research output: Contribution to journalArticle

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